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流化床-气流床耦合反应器中煤气化特性
  • ISSN号:0438-1157
  • 期刊名称:化工学报
  • 时间:2011
  • 页码:3484-3491
  • 分类:TQ028.8[化学工程]
  • 作者机构:[1]太原理工大学煤科学与技术教育部和山西省重点实验室,山西太原030024, [2]中国科学院山西煤炭化学研究所,山西太原030001
  • 相关基金:国家重点基础研究发展项目(2005CB22120102)国家自然科学基金项目(21076136).
  • 相关项目:煤/生物质共气化过程中协同作用的化学本质及热历程的调控
中文摘要:

利用化工动力学软件CHEMKIN建立了流化床-气流床耦合反应器等效网络模型,在Ф300mm反应器中的煤气化实验结果基础上,充分考虑耦合反应器不同区域物料间两相流动、传质传热,对耦合反应器各部分流体力学特征以及耦合反应器中不同区域的化学反应进行了分析。利用模型对飞灰的碳转化率、耦合反应器的碳转化率、耦合反应器内温分布及物料停留时间进行计算,结果表明,流化床耦合气流床反应器后,气流床可将出口飞灰碳转化64.1%,实现了耦合反应器对飞灰的再气化;耦合反应器煤气化系统的碳转化率由单独流化床的84.9%提高到92.2%。

英文摘要:

The carbon conversion from the fluidized bed coal gasification is about 85%. The fluidized bedentrained flow integrated coal gasifier was built with the aim to reuse the carbon in fly ash. A reactor network model was established by using the software CHEMKIN to study the reactions occurring in the integrated gasifier, and to investigate carbon re-gasification in fly ash. Based on experimental results on a 300 mm (i. d. ) integrated gasifier, the raw materials inter-phase flow, mass and heat transfer in different zones and the hydrodynamic characteristics of the integrated coal gasifier were analyzed. This model is to simplify the unstable continuity process in the integrated gasifier into a combination of ideal reactors, attempting to avoid the non-convergence of the study on complex flow field with many reactions with the CFD model. This model could be significant in the accurate analysis of new reactor concepts with sufficient knowledge of the hydrodynamic characteristics of reactors. Through the model, the carbon conversion rate of fly ash in the integrated coal gasifier, temperature profile and residence time of materials were recorded and calculated respectively. It was concluded that carbon conversion rate of fly ash reached 64.1 % in the entrained flow, and that the carbon in fly ash with low reactivity was re-gasified. Accordingly, the carbon conversion in the whole gasification system increased from 84.9% in the fluidized bed reactor to 92.2 % in the integrated coal gasifier.

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期刊信息
  • 《化工学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化工学会 化学工业出版社
  • 主编:李静海
  • 地址:北京市东城区青年湖南街13号
  • 邮编:100011
  • 邮箱:hgxb126@126.com
  • 电话:010-64519485
  • 国际标准刊号:ISSN:0438-1157
  • 国内统一刊号:ISSN:11-1946/TQ
  • 邮发代号:2-370
  • 获奖情况:
  • 中国科协优秀期刊二等奖,化工部科技进步二等奖,北京全优期刊奖,中国期刊方阵“双效”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:35185