中文摘要：

丝绸由原子转移激进分子聚合( ATRP )是用 2-hydroxyethyl methacrylate ( HEMA )的 grafted method.The 丝绸丝心蛋白的方面链上的氨基的组和氢氧根组与 2-bromoisobutyryl 溴化物( BriB-Br )被反应为 macroinitiator 是的 ATRP.And 获得有效 macroinitiator 有用 CuBr/N 水的水里的 HEMA 的 grafted ， N ，并且， N “， N ”单体集中的 -pentamethyldiethylenetriamine(PMDETA)as 催化剂 system.The 效果， CuBr 和 PMDETA 的比例， grafting temperatur

英文摘要：

Silk was grafted using 2-hydroxyethyl methacrylate（HEMA）by atom transfer radical polymerization（ATRP）method.The amino groups and hydroxyl groups on the side chains of the silk fibroin was reacted with 2-bromoisobutyryl bromide（BriB-Br）to obtain efficient macroinitiator for ATRP.And the macroinitiator was grafted with HEMA in water aqueous using CuBr/N,N,N＇,N＂,N＂-pentamethyldiethylenetriamine（PMDETA）as catalyst system.The effects of monomer concentration,the proportion of CuBr and PMDETA,grafting temperature and time on the silk grafting were discussed,and the optimal grafting technology was obtained.FT-IR characterization of the grafted silk showed a peak corresponding to HEMA,which indicated that HEMA was grafted onto the surface of silk.ATRP method could be applied on the silk modification and this technique provided a new way for silk grafting.