中文摘要：

利用中温水热技术合成了一种未见报道的三维超分子化合物[Cd（phen）C12]，并测定了其晶体结构．结果表明该化合物属于单斜晶系：C2／c空间群；晶胞参数a=16．949（3）nm，b=10．544（2）nm，c=7．2266（14）nm，α=90°，β=110．66（3）°，γ=90°，V=1208．4（4）nm^3，Z=4，R1=0．0341，ωR2=0．0839.

英文摘要：

A novel three dimensional supramolecular network cadmium halide compound with phen ligand was synthesized by mild hydrothermal techniques, and the synthesis and crystal structure of compound were discussed. The compound crystallized in the monoclinic, space group C2/c with a = 16. 949 （3）nm, b = 10. 544（2）nm, c = 7. 226 6（ 14）nm, α = 90°, β = 110.66（3）°, γ = 90°, V = 1 208.4（4）nm^3, Z = 4, R1 = 0.034 1, ωR^2 =0.081 6.