采用3D炭纤维预制体,以丙烯作为碳源,氮气作为载气,利用自制的快速CVI炉制备了C/C复合材料。详细分析了不同CVI工艺下,热处理对C/C复合材料断裂强度、断裂方式以及材料均匀性的影响。力学性能测试结果表明,材料的弯曲断裂特征与制备过程中受到的高温热处理次数有关。与1次连续CVI工艺相比,多阶段连续CVI工艺下,C/C复合材料经过2次“CVI-热处理”循环工艺后,其密度达1.8g/cm^3,抗弯强度达196.69MPa,断裂方式为假塑性断裂,材料在Weibull概率分布下强度分散性较小。
Using 3D carbon fibre preform, with C3H6 as the carbon source and N2 as the carrier gas, C/C composites are fabricated by the fast CVI process. The effects of heat-treatment on flexural strength, fracture ways and the uniformity of C/C composites are analyzed under different CVI processes. The experimental results indicate that the fracture characteristics of composites are closely related to the times of heat-treatment during CVI process. Compared with a continuous CVI, C/C composites show a pseudo-plastic fracture with the destiny 1.8 g/cm3 and flexural strength 196.69 MPa after two "CVI-heat treatment" circulation under multi-stage CVI process, and the uniformity of materials is well by Weibull distribution.