对福州市11个内河表层沉积物样品中15种多环芳烃(PAHs)含量进行了分析,结果表明,沉积物中15种PAHs的总量在84.3~2248.1μg/kg之间,均值为899.6μg/kg,处于中等污染水平,且呈现中部和南部高,东部、西部和北部低的地理分布特征.沉积物中15种PAHs的总量与有机碳总量(TOC)呈显著性正相关(r=0.7829,P〈0.05),其中11种PAHs含量与TOC之间呈显著性正相关(r=0.6557~0.9256,P〈0.05),且12种PAHs含量之间呈极显著性正相关(r=0.6706~0.9908,P〈0.01);.特征比值法对PAHs源解析的结果表明,沉积物中PAHs表现为混合源,并以本地交通污染源为主.以生物毒性评价标准对PAHs的生态风险进行了评价,有2个沉积物样品中的Ace、Flu和Phe超过了毒性效应低值(ERL),1个样品中的Ace和Flu超过了ERL值.从ERL商平均值大小来看,只有1个样品ERL商平均值〉1,具有一定的生态风险.
The concentrations of 15 PAHs in eleven surface sediment samples collected from inland rivers in Fuzhou City were analyzed. The results showed that the total concentrations of 15 PAHs ranged from 84.3 to 2248.1 μg/kg and the average was 899.6 μg/kg, which was at the intermediate pollution level. The geographical distribution of the total PAHs can be characterized by higher concentration in the southern and central region and lower concentration in the northern, eastern and western region of Fuzhou city. The total concentration of 15 PAHs had a significantly positive correlation with the total organic carbon concentration in sediments (r=0.7829, P0.05). Among the 15 PAHs, the concentration of 11 PAH isomers had significant positive correlations with the concentration of the total organic carbon (r=0.6557~0.9256, P0.05),and the concentration of 12 PAH isomers had highly significant correlations between each other (r=0.6706~0.9908, P0.01). The diagnostic ratios indicated that the sources of PAHs in sediments were mixed and mainly derived from local traffic pollution. The ecological risks of PAHs in sediments were evaluated according to the sediment quality guideline ERL (Effects Range Low). The concentrations of Ace, Flu and Phe in two sediment samples and those of Ace and Flu in one sediment sample exceeded ERL value. In the case of average ERL quotient of the PAH species, only one sediment sample had the average ERL quotient value greater than 1, and had certain ecological risks.