欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
考察了不同溶剂（如N-甲基吡咯烷酮、乙腈、聚乙二醇、1-甲基-3-己基咪唑六氟磷酸盐）以及不同共催化剂（如十六烷基三甲基溴化铵、四丁基溴化铵、溴化锂）对苯甲醛酰胺羰化反应的影响.与使用高沸点的有机溶剂N-甲基吡咯烷酮相比,使用乙腈、聚乙二醇和1-甲基-3-己基咪唑六氟磷酸盐作溶剂,反应后处理过程大大简化,反应界面更加友好.聚乙二醇作溶剂首次应用于酰胺羰化反应.
英文摘要：
The Palladium-catalyzed amidocarbonyhtion of benzaldehyde, acetarnide and CO using different co-catalysts in various solvents such as N-methylpyrrolidone （NMP）, acetonitrile, polyethyleneglycol（PEG） and 1-hexyl-3-methylimidazolium hexafluoropbosphate was investigated. The used co-catalysts included hexadecyl trimethyl ammonium bromide, tetrabutyl ammonium bromide, and lithium bromide. In contrast with high boiling point solvent NMP, the separation and purification of the product were greatly simplified and the reaction interface became more friendly using acetonitrile, PEG and 1-hexyl-3-methylimidazolium hexafluoropbosphate as solvents. For the first time PEG was employed as solvent in the reaction.
同期刊论文项目
同项目期刊论文
The synthsis of chiral functionalized polymers by alternatating copoly- -merization of propene and C
Asymmetric hydrogenation of aromatic ketones using new chiral-bridged diphosphine/diamine-Ru(II) com
A highly efficient chiral-bridged diphosphine ligand modified cationic Palladium (II) catalyst syste
New chiral monophosphite ligands modulated from BINOL and/or H8-BINOL bearing adamantyl substitutent
Synthesis of chiral bulky monophosphite ligands and their application in copper-catalyzed asymmetric
Pd-catalyzed asymmetric alternating co-polymerization of propene with carbon monoxide using ionic li
Rhodium-catalyzed asymmetric hydroformylation of vinylarenes with novel chiral P,N-ligands derived f
期刊信息
位置：