采用一套简单而又精确的相平衡研究装置,研究碳酸铯、氯化铯在乙醇水混合溶剂中的平衡溶解度,用Othmer-Tobias和Bancroft方程对该体系的饱和结线实验数据进行了关联.并且获得了两个液相的折光率,得到了体系的平衡互溶度和相关系,为进一步的应用研究提供了数据参考.
Liquid-liquid equilibrium data of Cs^+//CO3^2-,Cl^--C2H5OH-H2O system at 20℃ had been investigated by using a simple and accurate equilibrium apparatus. The saturated tie lines were described using the Othmer-Tobias and Bancroft equations. The mutual solubilities of salts in mixed solvent had been determined and the refractive index of the liquid phases was also determined.