采用类水滑石型混合金属氢氧化物(CdCr-LDH和ZnCdCr-LDH)为前驱体,通过气-固反应方法,制备了根植于层状氢氧化物层板中的硫化镉纳米晶和硫化镉/硫化锌复合纳米晶,通过改变前驱体(CdCr-LDH)中镉和铬的摩尔比可以调控硫化镉纳米晶的粒径.
The layered double hydroxide (LDH) compounds Cd0.7Cr0.3(OH)2(C12H25SO4)0.3·0.7H2O and Zn0.5Cd0.25Cr0.25(OH)2(C12H25SO4)0.25·1.7H2O were synthesized. Using these compounds as the precursors, we two types changing prepared CdS and CdS/ZnS nanocrystals that are implanted and stabilized in the layer matrices of the of compounds via a gas/solid reaction. The size of the nanocrystals can be controlled and tuned by the Cd/Cr molar ratio in the precursor.