中文摘要：

通过水热方法合成了6种Co（Ⅱ/Ⅲ）配合物Co（H2O）6.H2btec（1）;{[Co2（HCOO）6].CH3OH}n（2）;{[Co（4,4’-bipy）2（H2O）4].suc.4H2O}n（3）;Co（NA）2（H2O）4（4）;[Co（mal）（4,4’-bipy）H2O]n（5）;[Co（HCOO）4Co（H2O）4]n（6）（H4btec=均苯四甲酸,H2suc=丁二酸,HNA=烟酸,H2mal=丙二酸,bipy=联吡啶）},测试了配合物的UV-Vis吸收光谱和表面光电压光谱（SPS）,并通过X-ray单晶衍射确定了配合物的结构。它们的表面光电压光谱在300~800 nm范围内均表现出正的光伏响应,并将其与UV-Vis吸收光谱进行了分析和对比,发现SPS中表面光伏响应带与UV-Vis吸收光谱的吸收峰具有良好的对应关系。通过对比6种配合物的SPS可以看出,中心金属离子的价态、配位模式及配位微环境均对SPS响应带的位置和形状有一定影响。

英文摘要：

Six cobalt complexes,Co（H2O）6·H2btec（1）;{[Co2（HCOO）6]·CH3OH}n（2）;{[Co（4,4＇-bipy）2（H2O）4]·suc·4H2O}n（3）;Co（NA）2（H2O）4（4）;[Co（mal）（4,4＇-bipy）H2O]n（5） and [Co（HCOO）4Co（H2O）4]n（6）,were synthesized through hydrothermal method.UV-Vis absorption spectra and surface photovoltage spectra of the complexes were detected and the structures of the complexes were determined by single-crystal X-ray diffraction.There are positive responses in the range of 300-800 nm in the SPS.There are good corresponding relationships between response bands of SPS and absorption peaks of UV-Vis absorption spectra by the comparison.Comparing the SPS of six complexes,the valence,coordination mode and coordination micro-environment affect the position and the shape of the response bands.