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锶掺杂铅酸钡陶瓷的热电性能
  • 期刊名称:硅酸盐学报, 34(2):137-141. 2006 (EI)
  • 时间:0
  • 分类:O611[理学—无机化学;理学—化学]
  • 作者机构:[1]华东理工大学机械与动力工程学院,上海200237, [2]中国科学院上海硅酸盐研究所,超微结构与高性能陶瓷国家重点实验室,上海200050
  • 相关基金:国家自然科学基金(50472046);上海市曙光计划资助项目.
  • 相关项目:高性能热电薄膜氢气传感器的研究
中文摘要:

用固相反应法对BaPbO3材料进行了Sr掺杂,合成了Ba1-xSrxPbO3(0≤x≤1.0)系列粉体材料。对样品进行了X射线衍射分析。通过计算获得了材料的晶胞参数随化学组分的变化规律。将粉体烧结成块状陶瓷,在300~673K测试了该陶瓷的电导率、Seebeck系数和热导率随Sr掺杂量(x)和温度的变化情况。结果发现:随x的增加,晶胞参数(a,b,c)缩短,晶胞体积(V)收缩,晶格对称性降低。Seebeck系数的绝对值升高,热导率降低,电导率下降。当x=0.6时,Ba1-xSrxPbO3表现出高的品质因子Z,在673K时,Z的最大值达1.2×10^-4/K。

英文摘要:

Powder samples of Ba1-xSrxPbO3 (0≤x≤1. 0) were synthesized by solid state reaction and their phase structures were investigated by X-ray diffraction analysis. Lattice parameters were calculated as a function of cherhical compositions. The thermoelectric properties of sintered pellets were measured at 300-673 K. The results show that the lattice lengths of the a, b and c axis gradually decrease with increase of Sr content, causing a shrinkage of cell volume and a reduction of crystal symmetry. The absolute value of the Seebeck coefficient increases with Sr content, while thermal conductivity and electrical conductivity decreases. The high values of figures of merit Z are obtained at x=0. 6, and the maximal value is 1.2×10 ^-4/K at 673 K.

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