对2003.11采自北京东南郊化工区的土壤、植物样品中11种氯苯类有机物进行了分析测定.结果表明,土壤(干重)中氯苯类有机物(CBs)的总量范围为0.232—51.15ng·g^-1,均值为18.16ng·g^-1,其中1,2-DCB、1,4-DCB和HCB分别占45.2%、15.3%和17.1%;植物(干重)中CBs的总量范围为5.635—31.99ng·g^-1,均值为12.36ng·g^-1,其中1,4-DCB和HCB分别占51.5%和14.9%.土壤中∑CBs与土壤有机质含量的皮尔森(Pearson)相关系数为0.544(P≤0.05),呈弱正相关关系.此外,除1,4-DCB和1,2,4-TCB外,云杉针叶中CBs的土壤.植物富集因子(BCFa)随CBs挥发能力[lg(VP/KOW)的增强而降低,随CBa辛醇/空气分配系数(KOA)的增大而升高.
Eleven chlorobenzenes (except MCB of a total of 12 in the congener series, CBs) in soil and plant samples collected from Beijing southeast chemical industry zone were analyzed. The range of total chlorobenzenes was 0.232 - 51.15 ng·g^-1 in soil (dry weight), among which 1,2-DCB, 1,4-DCB and HCB occupy 45.2%, 15.3% and 17.1% respectively; while 5.635 - 31.99 ng·g^-1 in plants (dry weight), among which 1,4-DCB and HCB occupy 51.5% and 14.9%. Total CBs concentrations in soil were positive related with soil organic matter ( r =0.544, p ≤0.05). Soil-to-spruce needle bioconcentration factors (BCFs) of CBs were calculated and their relationships with CBs' physicochemical properties were investigated. Except for 1,4-DCB and 1,2,4-TCB, the CB BCF into spruce needle generally decreased with increasing volatilization potential [ lg( VP/KOW )], and increased with increasing KOA.