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再生水中亚硝酸盐对余氯衰减的影响及其控制
  • ISSN号:0493-2137
  • 期刊名称:天津大学学报
  • 时间:2013.5.31
  • 页码:423-428
  • 分类:X703.1[环境科学与工程—环境工程]
  • 作者机构:[1]天津大学环境科学与工程学院,天津300072
  • 相关基金:国家自然科学基金资助项目(51178303);国家水体污染控制与治理科技重大专项资助项目(2009ZX07317-005-01).
  • 相关项目:供水管网性能综合评价与多目标更新优化模型研究
中文摘要:

根据华北地区某再生水厂的实际水质特点,通过实验比较了加氯消毒后水中TOC、NO2-对余氯消耗的影响;使用平行一级反应模型分析实验结果,发现折点氯化后亚硝酸盐耗氯反应的速率常数显著高于有机物耗氯反应,亚硝酸盐成为再生水中重要耗氯物质.为稳定再生水中余氯浓度,提出了2个方案:再生水中加氨或调节pH值,分别进行了模型拟合和实验效果分析.通过对比加氨和调pH值方案的余氯成分和所需药剂投量,得出调节水体至弱碱性(pH值为8.3)是更好的途径.本研究对再生水厂消毒工艺的设计、运行具有一定的借鉴意义,对保证再生水水质安全具有较高的实用价值.

英文摘要:

Based on the water samples collected from a reclaimed water treatment plant (RWTP) in North China, the effect of nitrite and TOC on chlorine decay was investigated and a parallel first-order decay model was used to simulate the experimental data. The result indicated that the reaction constant between nitrite and chlorine was higher than that between organic matter and chlorine; and nitrite consumed much more chlorine than organic matter after break- point chlorination. In order to stabilize the chlorine concentration in reclaimed water, two methods were proposed to restrain nitrite-leaded chlorine decay: adding ammonia and adjusting water to be alkaline before chlorination, each of which was tested by experiments and simulated with parallel first-order decay models. It is proven that the two meth- ods were both effective in stabilizing residual chlorine concentration. And then the residual-chlorine composition and chemical dosage of the two proposed methods were compared, and the result showed that adjusting water to be alkalescent (pH=8.3) was better than ammonia addition, and thus the former method was recommended to be applied in the plant.

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期刊信息
  • 《天津大学学报:自然科学与工程技术版》
  • 北大核心期刊(2011版)
  • 主管单位:
  • 主办单位:天津大学
  • 主编:单平
  • 地址:天津市南开区
  • 邮编:300072
  • 邮箱:
  • 电话:022-27403448
  • 国际标准刊号:ISSN:0493-2137
  • 国内统一刊号:ISSN:12-1127/N
  • 邮发代号:6-27
  • 获奖情况:
  • 中国期刊方阵双效期刊
  • 国内外数据库收录:
  • 美国数学评论(网络版),美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:6410