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Ni75Al5Cr20合金中预析出相的微观相场模拟
  • ISSN号:0412-1961
  • 期刊名称:《金属学报》
  • 时间:0
  • 分类:TG111.5[金属学及工艺—物理冶金;金属学及工艺—金属学]
  • 作者机构:[1]西北工业大学凝固技术国家重点实验室,西安710072
  • 相关基金:国家自然科学基金项目50941020 10902086和50875217; 陕西省自然科学基金项目SJ08-ZT05和SJ08-B14; 西北工业大学研究生种子基金项目Z2010014资助~~
中文摘要:

采用微观相场法模拟了Ni(75)Al5Cr(20)合金的时效过程,研究了Cr和Al原子在无序fcc固溶体(001)和(002)面上序参数变化与相结构演化之间的关系.结果表明,合金时效序列为:无序基体→L10(M=1)预析出相→DO(22)相.在时效的最初阶段,原子只在面内跃迁,发生面内原子有序化,形成L10(M=1)结构;此后,原子在面间跃迁,原子在(001)面上进一步有序化,在(002)面上无序化,L10(M=1)结构向DO(22)结构转变.随温度降低,L10(M=1)预析出相孕育期和存在期缩短,从而导致DO(22)相的孕育期缩短;L10(M=1)预析出相在低温下容易形成.

英文摘要:

DO_(22) phase with long period ordered structure is the main strengthening phase in Ni-Al-Cr alloy applied in high temperatures,as it hinders the slipping of dislocations during the deformation.Structure transformation from fcc to DO_(22) during the ordering process and phase separation have been studied extensively,but there are only a few of reports on the phase transformation in early precipitation stage,especially on the phase transformation of metastable pre-precipitate.In this paper,the microscopic phase-field method was employed to study the pre-precipitate during the transformation from fcc to DO_(22) in Ni_(75)Al_5Cr_(20) alloy.The early ordering process of Ni_(75)Al_5Cr_(20) alloy are simulated at four different temperatures,and the relationship between the order parameter evolutions of Cr and Al atoms on(001) and(002) planes of disordered fcc solid solution and structure evolution will be investigated.The simulation results demonstrate that the parent phase transformed into Llo(M=1) pre-precipitate with long period ordered structure before DO_(22) phase formed.At the early aging stage,the atomic ordering is proceeded on each plane as the atoms migrate on planes only,and the L1_0(M=1) pre-precipitate formed in the way of congruent ordering.Then,the further ordering of atoms on(001) plane was induced by the migration of atoms between different planes,and the pre-precipitate with L1_0(M=1) structure is gradually transformed into DO_(22) phase.The incubation period and existent time of L1_0(M=1) phase are prolonged with the temperature increasing,as a result,the incubation period of DO_(22) phase is longer when the aging temperature is higher,and the formation of L1_0(M=1) pre-precipitate is easier when the temperature is lower.

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期刊信息
  • 《金属学报》
  • 中国科技核心期刊
  • 主管单位:中国科学协术协会
  • 主办单位:中国金属学会
  • 主编:柯俊
  • 地址:沈阳文化路72号
  • 邮编:110016
  • 邮箱:shxiao@imr.ac.cn
  • 电话:024-23971286
  • 国际标准刊号:ISSN:0412-1961
  • 国内统一刊号:ISSN:21-1139/TG
  • 邮发代号:2-361
  • 获奖情况:
  • 第一、二届全国优秀科技期刊评比一等奖,第一、二、三届国家期刊奖,国家期刊方阵"双高"期刊,第一、二、三届中国科学院科技期刊评比一等奖,中国科学院优秀期刊特别奖,第一、二、三、五届中国科协优秀科技期刊评比一等奖,中国科协精品期刊工程A类、B类,第一、二、三、四、五届中国百种杰出学术期刊,首届出版政府奖
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  • 被引量:26785