中文摘要：

有 3-methylpenta-3,4- dien-2-one 或 3-benzylpenta-3,4-dien-2-one 的 sulfonyl aldimines 或芳基醛的尝试的 Baylis-Hillman 反应给了相应 Baylis-Hillman 分别地在 DBU 或 PMe3 的催化作用下面在 DMSO 在中等收益使内收。中等 diastereoselectivities 在 3-benzylpenta-3,4-dien-2-one 的反应被观察， N-arylmethylidene-1-naphthalenesulfonamides 由 chiral 催化剂辛可宁碱衍生物 TQO 催化 {4-(3-ethyl-4-oxa-1-azatricyclo [4.4.0.03,8 ] dec-5-yl ) quinolin-6-ol } 。

英文摘要：

The attempted Baylis-Hillman reactions of sulfonyl aldimines or aryl aldehydes with 3-methylpenta-3,4-dien-2-one or 3-benzylpenta-3,4-dien-2-one gave the corresponding Baylis-Hillman adducts in moderate yields in DMSO under the catalysis of DBU or PMe3, respectively. Moderate diastereoselectivities were observed in the reaction of 3-benzylpenta-3,4-dien-2-one with N-arylmethylidene-1-naphthalenesulfonamides catalyzed by chiral catalyst cinchona alkaloid derivative TQO {4-（3-ethyl-4-oxa-1-azatricyclo[4.4.0.0^3,8]dec-5-yl）quinolin-6-ol}.