卟啉和多酸都具有结构可变、电子可调、拓扑多样等特点,通过构型设计、金属络合以及给受体取代等进行调控后,兼具无机材料和有机材料优势,在非线性光学、敏化太阳能电池等领域较好应用前景。本文概述了多酸基卟啉衍生物近期的理论研究工作进展。
Porphyrins and polyoxometalates (POMs) generate new multifunctional hybrid materials because of their potential applications in the area of nonlinear optical, dye-sensitized solar cells, et al. Such materials not only combine the advantages of organic materials but also contribute to explore the possible synergistic effects. This paper provides a brief overview of recent progress in the density functional theory (DFT) study on POMs-porphyrin derivatives.