通过在真空条件下将氯铂酸的乙醇溶液引入到钛酸纳米管内,再经过热处理制备了镶嵌铂的纳米管钛酸(简写为PNTA).X射线光电子能谱(XPS)表明氯铂酸大部分转变成pt^0和PtO,顺磁共振谱(ESR)表明在PNTA中生成了束缚单电子的氧空位,在紫外-可见扩散漫散射谱(DRS)谱上表现出对可见光有吸收能力.丙烯的可见光光催化氧化实验结果表明:在可见光激发下(A〉420nm),PNTA对丙烯的光催化去除反应具有活性.
Pt-inserted nanotube titanic acid (abbr. PNTA) was prepared as follows: H2PtCl6 ethanol solution was filled into the titanic acid nanotubes and then annealed in air at 673 K for 3 h. X-ray photoelectron spectroscopy (XPS) showed that H2PtCl6 has been converted to Pt^0 and PtO. The result of electron spin resonance (ESR) revealed that there are single-electron-trapped oxygen vacancies to be formed in PNTA after heat treatment in air. Under visible light ( A 〉 420 nm), propylene can be catalytically oxidized by PNTA in the presence of air.