采用化学法在氧化石墨烯(GO)表面垂直生长出聚苯胺(PANI)纳米线阵列。利用SEM、FT-IR、Raman对所制备的GO/PANI复合材料的形貌及结构进行表征。该复合材料的电化学电容性能通过循环伏安(CV)、交流阻抗(EIS)和恒流充放电进行表征。研究结果表明:在0.2A/g的电流密度下,GO/PANI电极首次充放电比电容可高达469F/g,高于纯PANI电极的452F/g,复合材料的电荷传递电阻为1Ω·cm^2。同时,GO/PANI的循环稳定性及倍率特性得到极大的增强。
We introduced a facile chemical polymerization method to construct nanocomposites by combining conduc-ting polyaniline (PANI) nanowires arrays with graphene oxide (GO) nanosheets. The surface morphology and structure of nanocomposites are characterized by SEM, FT-IR, Raman measurements. Electrochemical properties were character-ized by cyclic voltammetry(CV), electrochemical impedance spectroscopy (EIS) and gaivanostatic charge/discharge. The results indicated that the average specific capacitance of nanocomposites could be as high as 469 F/g in the potential range from 0 to 0. 7V at a current density of 0. 2 A/g, higher than pure PANI electrode (452 F/g), showing a synergistic of PANI and GO. The charge transfer resistance (Rct) of GO/PANI was 1 Ω· cm^2. They also exhibited greatly to improve electrochemical stability and rate performances.