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中文摘要：
在三氟化硼乙醚中通过阳极氧化二甲基甲撑二氧苯获得了新型导电高分子聚（二甲基甲撑二氧苯）。二甲基甲撑二氧苯的起始氧化电位是0．7V（vsSCE），远小于在含0．1mol／L四氟化硼四丁基铵的乙腈中的起始氧化电位1．57V（vsSCE）、聚合物的电导率为0．23S／cm。红外和核磁表明聚（二甲基甲撑二氧苯）的聚合位点在4和5位；
英文摘要：
2,2 -dimethyl- 1,3 -benzodioxole was electropolymerized in boron trifuoride diethyl etherate and a novel conducting polymer poly （2,2 - dimethyl - 1,3 - benzodioxole） was eleetrodeposited. The oxidation potential onset of 2,2 - dimethyl - 1,3 - benzodioxole was initiated at 0.7 V versus a saturated calomel electrode （SCE） , which was much lower than that determined in aeetonitrile containing 0.1 M tetrabutylammonium tetrafluoroborate （1.57 V vs. SCE）. Poly（2,2 -dimethyl -1,3 -benzodioxole） films obtained from boron trifuoride diethyl etherate showed an electrical conductivity of 0.23 S cm - 1. IR and NMR studies showed that the polymerization of 2,2 - dimethyl- 1,3 -benzodioxole occurred at C4 and C5 position.
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