以四氟化钛为前驱物、P123为表面活性剂、柠檬酸为稳定剂、盐酸为酸性调节剂、氟化铵为添加剂,利用水热方法首次制备出暴露{111}面的截顶点四棱双锥锐钛矿多面体.通过XRD,SEM,TEM,HRTEM,SEAD和EDX对所制备的多面体的组成、结构和形貌进行了分析和表征.结果显示:柠檬酸和氟化铵的使用,有利于锐钛矿多面体的取向生长和{111}晶面的保留.同时研究发现,所制备的多面体在碱性和紫外光照条件下对亚甲基蓝(MB)具有很好的催化活性和降解效果,显示出潜在的应用价值.
Polyhedrons of truncated anatase bipyramids with exposure of { 111 } facets were hydrothermally synthesized from hydrolysis of TiF4 in the presence of NH4F, HC1, and tri-block copolymer P123 using citric acid monohydrate as a stabilizer. The phase, crystal structure, morphology, chemical composition and property of the anatase polyhedrons were characterized by various techniques of X-ray diffraction (XRD), transmission electron microscopy (TEM), high- resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), selected area electron diffraction (SEAD), energy-dispersive Xray spectrometry (EDX) and UV radiations, and their high performances in photo-degradation of methylene blue (MB) under alkaline conditions were specifically recognized.