中文摘要：

原子转移自由基聚合（ATRP）是一种活性自由基聚合方法，通过它可以合成结构可控的官能性聚合物．双官能性聚合物是制备嵌段聚合物和模型网络的前驱体，具有较大的理论和应用价值，寻求新的双官能引发剂以获得末端官能性聚合物已经成为当前ATRP研究领域的重要研究方向之一,根据报道，

英文摘要：

3-Chloro-2-（chloromethyl）-1-propene （CCMP） was synthesized and used to initiate atom transfer radical polymerization （ATRP） of styrene catalyzed by copper （ Ⅰ ） chloride/2,2′-bipyridine at 125℃. As a difunctional initiator, CCMP can initiate ATRP of styrene with two living end sites at the same time. The structure of the obtained α,ω-chloropolystyrene was confirmed by ^1H-NMR spectra. The living character of the ATRP process is indicated by narrow molecular weight distributions of the obtained polystyrene （Mw/Mn 〈 1.5）, a linear In（ [ M]0/[ M] ） versus time profile and predictable molecular weights proportional to monomer conversion.