Study on the reactions of azo compounds with acyl halides mediated by Sm/TiCl4
- ISSN号:1673-1581
- 期刊名称:《浙江大学学报:B卷英文版》
- 时间:0
- 分类:O622.6[理学—有机化学;理学—化学]
- 作者机构:[1]Department of Chemistry, Zhefiang University, Hangzhou 310028, China, [2]State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
- 相关基金:Project (No. 20072033) supported by the National Natural Science Foundati on of China and Specialize dRe search Fund for the Doctoral Program of Higher Education of Chia
中文摘要:
酰胺能被获得在对由 Sm/TiCl4 的优秀产量好 N=N 的调停的减少的劈开在偶氮的混合物结合;在一个壶的连续酰化作用。它直接从很简单的开始的材料为酰胺的合成提供一个其他的方法。
英文摘要:
Amides can be obtained in good to excellent yield by Sm/TiCl4 mediated reductive cleavage of N=N bond in azo compounds and successive acylation in one pot. It offers an alternative method for the synthesis of amides from very simple starting materials directly.