欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
采用免焙烧法制备催化剂前驱体,用H2等离子体还原制备免焙烧的MoP（NC-MoP）催化剂和Ce改性的MoP（Ce-MoP（n））催化剂。对制备的催化剂进行XRD和N2物理吸附表征,并用质量分数为0.8%的二苯并噻吩/十氢萘（DBT）溶液来考察催化剂的加氢脱硫（HDS）反应活性。与焙烧的MoP（C-MoP）催化剂相比,NC-MoP具有较小的颗粒尺寸和较大的比表面积,从而具有较高的DBT加氢脱硫反应活性;引入Ce后,催化剂的颗粒尺寸降低,比表面积增加,反应活性提高;Ce含量较低时,助催化效果随着Ce含量的增加而增强,Ce-MoP（0.3）具有最高的反应活性。
英文摘要：
Non-calcinated MoP （NC-MoP） and Ce promoted MoP （Ce-MoP（n）） catalysts were prepared by a non-calcination procedure, in which the precursors were directly converted to the active phosphide phase using the H2 plasma reduction （PR） method. The morphologies of the catalysts were characterized by XRD and N2 physical adsorption, and the hydrodesulfurization （HDS） performances were studied with a model fuel containing 0.8% （ mass fraction）dibenzothiophene （DBT） in decalin. Compared with the calcinated MoP （C-MoP） , NC-MoP possessed smaller particle size and larger specific surface area, leading to higher HDS activity. The introduction of Ce promoted the HDS activity, caused by the decrease of the particle size. At lower content of Ce, the promotion effect increased with the increase of Ce content, and Ce-MoP （0. 3） expressed the highest HDS performance.
同期刊论文项目
同项目期刊论文
Decomposition of hydrogen sulfide in non-thermal plasma aided by supported CdS and ZnS semiconductor
Decomposition of Hydrogen Sulfide in Non-Thermal Plasma Aided by Supported ZnxCd1-xS Solid Solutions
Hydrodesulfurization of 4,6-dimethyldibenzothiophene and its hydrogenated intermediates over bulk Ni
Highly acidic mesoporous aluminosilicates assembled from zeolitic subunits generated by controllable
Different role of H2S and dibenzothiophene in the incorporation of sulfur in the surface of bulk MoP
Synthesis of 4,6-Dimethyldibenzothiophene and 1,2,3,4-Tetrahydro-4,6-dimethyldibenzothiophene via Ti
Creation of Oxygen Vacancies in MoO3/SiO2 by Thermal Decomposition of Pre-Impregnated Citric Acid Un
Oxidative Desulfurization of Dibenzothiophene over Tungsten Oxides Supported on SiO2 and gamma-Al2O3
Hydrothermal synthesis of ionic liquid [Bmim]OH-modified TiO2 nanoparticles with enhanced photocatal
期刊信息
位置：