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Concentrations, profiles and gas-particle partitioning of PCDD/Fs, PCBs and PBDEs in the ambient air of an E-waste dismantling area, southeast China
  • ISSN号:0023-074X
  • 期刊名称:《科学通报》
  • 时间:0
  • 分类:X831[环境科学与工程—环境工程]
  • 作者机构:[1]State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, ChineseAcademy of Sciences, Beijing 100085, China
  • 相关基金:Supported by the National Natural Science Foundation of China (Grant No. 20607025, 20777079 and 20737007)
中文摘要:

Polychlorinated diebenzo-p-dioxins (PCDD ) , polychlorinated diebenzofurans (PCDF ) , polychlorinated (印刷电路板) 和 polybrominated diphenyl (PBDE ) 在 Taizhou,拆除东南中国的区域评估他们的集中的电子浪费,侧面并且煤气粒子的划分的周围的空中被监视。三角洲 PCDD/Fs 集中从 2.91 ~ 50.6 pg/m (3 ),与 14.3 pg/m (3 ) 的一般水准。为 PCDD/Fs 的 I-TEQs 在 0.20-3.45 pg/m (3 ) 的范围,与 1.10 pg/m (3 ) 的一般水准。西格马印刷电路板集中和 TEQ 从 4.23 ~ 11.35 ng/m (3 ), 0.050 ~ 0.859 pg (TEQ )/m (3 ) 分别地。西格马 PBDE 的集中从 92 ~ 3086 pg/m (3 ),与 894 pg/m (3 ) 的一般水准。PCDD/Fs,印刷电路板和 PBDE 的污染层次比另外的城市的地点高,它可以与拆除活动的电子浪费被联系。而印刷电路板在煤气的阶段主导地散布了, PCDD/Fs 专门在粒子阶段被发现。划分也是的 gas-partilce 与使过冷的液体蒸汽压力(P-L (0 )) 由相关估计了煤气粒子的分配系数(K-p ) 。PCDD/Fs,印刷电路板和 PBDE 的测量微粒吸着与从 Junge-Pankow 模型和洋槐的一种吸收模型的预言相比。Junge-Pankow 模型很好估计了印刷电路板的微粒部分。然而,它低估了 PCDD/Fs 的吸着并且过高估计 PBDE 的部分。从与测量数据适合很好的洋槐的一种模型的 PCDD/Fs 和印刷电路板的预言的微粒部分。

英文摘要:

Polychlorinated diebenzo-p-dioxins (PCDDs), polychlorinated diebenzofurans (PCDFs), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) were monitored in the ambient air of Taizhou, an E-waste dismantling area of southeast China to evaluate their concentrations, profiles and gas-particle partitioning. The ∑PCDD/Fs concentrations ranged from 2.91 to 50.6 pg/ma, with an average of 14.3 pg/ma. The I-TEQs for PCDD/Fs were in the range of 0.20-3.45 pg/ma, with an average of 1.10 pg/ma, The ∑PCBs concentrations and TEQs ranged from 4.23 to 11.35 ng/ma, 0.050 to 0.859 pg(TEQ)/ma, respectively. The concentrations of ∑PBDEs ranged from 92 to 3086 pg/ma, with an average of 894 pg/ma, The pollution levels of PCDD/Fs, PCBs and PBDEs were higher than other urban sites, which may be associated with the E-waste dismantling activities. The PCDD/Fs were found exclusively in the particle phase whereas PCBs distributed dominantly in the gas phase. The gas-partilce partitioning was also assessed by correlating the gas-particle partition coefficient (Kp) with the subcooled liquid vapor pressure (pL^0). The measured particulate sorptions of PCDD/Fs, PCBs and PBDEs were compared with the predictions from Junge-Pankow model and Koa absorption model. The Junge-Pankow model well estimated the particulate fractions of PCBs. However, it underestimated the sorptions of PCDD/Fs and overestimated the fractions of PBDEs. The predicted particulate fractions of PCDD/Fs and PCBs from Koa model fitted well with the measured data.

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期刊信息
  • 《科学通报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院
  • 主编:周光召
  • 地址:北京东黄城根北街16号
  • 邮编:100717
  • 邮箱:csb@scichina.org
  • 电话:010-64036120 64012686
  • 国际标准刊号:ISSN:0023-074X
  • 国内统一刊号:ISSN:11-1784/N
  • 邮发代号:80-213
  • 获奖情况:
  • 首届国家期刊奖,中国期刊方阵“双高”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国数学评论(网络版),美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:81792