采用配位均匀共沉淀法制备出ZnO/Ag/CdCO,纳米复合光催化剂,用TEM、XRD、FT—IR、ICP等对产物的形貌、微观结构及组成进行了表征,着重研究了反应物配比及Cd(NO3)2浓度对ZnO/Ag/CdCO3纳米复合光催化剂催化降解甲基橙光催化活性的影响规律,结果表明,n(Zn^2+):n(Ag^+):n(Cd^2+)=21:1.76:1.75,Cd(NO3)2浓度为0.168mol·dm^-3时制得的纳米复合光催化剂对甲基橙(MO)的降解率较ZnO/Ag提高51%,ZnO/Ag/CdCO,对MO的光催化降解符合一级反应动力学方程,表观速率常数为1.4551h^-1,是ZnO/Ag的7倍。
The ZnO/Ag/CdCO3 nanocomposite photocatalysts were prepared by coordination-coprecipitation method. The morphology, microstructure and component were characterized by TEM, XRD, FT-IR, and ICP. The influence of reactants ratio and Cd (NO3)2 concentrations on the photocatalytic activity for methyl orange photodegradation over ZnO/Ag/ CdCO3 were studied. The result indicated that the photodegradation ratio of methyl orange over ZnO/Ag/CdCO3 nanocomposite photocatalysts, which were prepared by selecting n (Zn2+):n (Ag+):n (Cd2+) molar ratio of 21:1.76:1.75 and Cd(NO3)2 concentration of 0.168 mol·dm^-3, increased 51% compared to ZnO/Ag. The photo degradation ratio of methyl orange over ZnO/Ag/CdCO3 according with first-order reaction kinetics equation and the determined reaction-rate constant (k) of ZnO/Ag/CdCO3 was 1.4551 h^-1 which was 7 times bigger than ZnO/Ag.