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Detection of Picric Acid by Terpy-Based Metallo- Supramolecular Fluorescent Coordination Polymers in Aqueous Media
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 时间:0
  • 分类:O634[理学—高分子化学;理学—化学] O438[机械工程—光学工程;理学—光学;理学—物理]
  • 作者机构:[1]School of Chemistry and Chemical Engineering, Hefei University of Technology and Anhui Key Laboratory of Advanced Functional Materials and Devices, Hefei, Anhui 230009, China, [2]Jiangsu Provincial Key Laboratory for Numerical Simulation of Large Scale Complex Systems (NSLSCS), School of Physical Science and Technology, Nanjing Normal University, Nanjing, Jiangsu 210023, China
  • 相关基金:This work is supported by the National Natural Sci- ence Foundation of China (Nos. 21371043 and 21302035), and the Fundamental Research Funds for the Central Universities (No. 2014HGCH0009). Y.-Y.Z. expresses the most sincere respect to Prof. Xi-Kui Jiang (Shanghai Institute of Organic Chemistry) and Prof. Zhan-Ting Li (Fudan University) for sustained encour- agement and support for his research.
中文摘要:

合成二线性基于 terpy metallo 超分子荧光灯通过有 ditopic terpyridine ligand 的 Zn 2+ 和 Cd 2+ 离子的 11 complexation 的协作聚合物被报导。P1 和 P2 的可分散性显著地通过吸水的 oligo-ethyoxy 方面链的介绍在器官的溶剂和水被改进。二聚合物由于在 d 10 金属离子和结合的分隔符单位之间的 intra-ligand 费用转移(ILCT ) 在解决方案和稳固的状态两个都显示了黄轻排放。这些协作聚合物作为荧光灯被探索为在水的媒介,显示的高敏感和好选择检测苦酸酸的 chemosensors。另外,测试脱衣从这些聚合物被准备并且展出了为公共安全和安全在室外的水里检测 NAC 污染物质的实际潜力。

英文摘要:

The synthesis of two linear terpy-based metallo-supramolecular fluorescent coordination polymers through 1 : 1 complexation of Zn^2+ and Cd^2+ ions with ditopic terpyridine ligand was reported. The dispersibility of P1 and P2 was significantly improved in organic solvent and water through the introduction of hydrophilic oligo-ethyoxy side chain. Two polymers displayed yellow light emission both in solution and the solid state due to the intra-ligand charge transfer (ILCT) between the d^10 metal ions and the conjugated spacer unit. These coordination polymers were explored as fluorescent chemosensors for detecting picric acid in aqueous media, displaying high sensitivity and good selectivity. In addition, test strips were prepared from these polymers and exhibited the practical potential of detecting the NACs pollutants in the outdoor water for public safety and security.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175