在Pd/C催化下,以甲酰肼为还原剂,卤代芳烃通过还原偶联反应能高选择性地合成相应的联苯化合物.具有不同取代基的卤代芳烃的还原偶联反应产率在52%-94%之间.
The reductive coupling of aryl halides to form the corresponding biaryls was effected with high selectivity in water, using formic hydrazide as a reducing agent in the presence of a catalytic amount of Pd/C. Various substituted aryl halides proceed smoothly to afford the corresponding biaryls with good yields in the range of 52%-94%.