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PTW对PA1010/PP共混物的增容作用
  • ISSN号:0251-0790
  • 期刊名称:《高等学校化学学报》
  • 时间:0
  • 分类:O631.11[理学—高分子化学;理学—化学] TQ325.3[化学工程—合成树脂塑料工业]
  • 作者机构:[1]河南科技学院化学化工学院,新乡453003, [2]四川大学高分子科学与工程学院,高分子材料工程国家重点实验室,成都610065
  • 相关基金:国家自然科学基金(批准号:50533050,50873063,20874064)资助.
中文摘要:

为了增加聚酰胺10101聚丙烯(PA1010/PP)共混物的相容性,提高共混物的力学性能,采用一种新型的反应型增容剂——乙烯-丙烯酸丁酯-甲基丙烯酸缩水甘油酯共聚物(PTW)进行增容,通过扫描电镜(SEM)、力学性能、傅里叶变换红外光谱(FTIR)和差示扫描量热(DSC)测试,研究了PTW对PA1010/PP共混物的增容作用.结果表明,随着唧的加入,共混物的相区尺寸明显变小,当PA1010/PP/PTW质量比为70:30:7时,分散相尺寸细小而均匀,表明P1IW有较好的增容作用.FTIR结果表明,PTW上的环氧基团和PA1010在熔融共混中发生了化学反应.DSC研究结果表明,PA1010的结晶温度随PTW的加入而降低,说明PTW对PA1010结晶有抑制作用.另外,PTW的加入使PP的结晶温度下降,当删质量分数为5%时出现2个结晶峰,即出现异相成核结晶和均相成核结晶,PP均相成核结晶的出现从另一个方面说明,在PA1010基体中分散相PP尺寸非常细小.当唧质量分数为7%时共混物的力学性能最佳,干态冲击强度达到13.93kJ/m2,是未加增容剂时的2倍,拉伸和弯曲性能基本不变.PTW的增容机理在于其分子链中的甲基丙烯酸缩水甘油酯能与PA1010发生化学反应,而乙烯链段与PP有较好的亲和性,从而降低界面张力,减少相区尺寸,大幅度提高力学性能.

英文摘要:

In order to improve the compatibility and the mechanical properties of Polyamide1010 and Polypro- pylene(PA1010/PP) blends, a novel reactive compatibilizer ethylene-butylacrylate-glycidyl methacrylate terpolymer(PTW) was used to compatibilize the blends. The compatibilizing effect of PTW on PA1010/PP blends was investigated by means of scaning electron microscopy ( SEM ), Fourier transform infrared ( FFIR), mechanical testing and differential scaning calorimetry( DSC), respectively. It was found that with increasing the PTW content, the size of the dispersed PP particles decreased obviously, when the mass ratio of PA1010/ PP/PTW is 70: 30: 7, the domain size showed a fine and uniform dispersion in the matrix,indicated FFW had an effective compatibilization effect on PA1010/PP blends. FTIR results show that the epoxy groups of PTW react with the end group of PAl010 in the blending process. DSC results show that the addition of PTW decreased the crystallization temperature of PAl010, indicate that PTW has an inhibition effect on the crystal- lization of PAl010. On the other hand, with increasing the mass fraction of PTW content, the crystallization temperature of PP became lower too, when the mass fraction of PTW was 5 %, two crystalline peaks appeared, the crystallization of PP at the lower temperature should be assigned to homogeneous nucleation, the other one was heterogeneous nucleation. The appearance of howogennous nucleation demonstrated that the size of PP particles was very fine in the matrix from the other hand. When the mass fraction of PTW was 7%, the blend had the best comprehensive property and the izod impact strength of dried samples was 13.93 kJ/m2, which is 2 times that for the binary PA1010/PP blend. Meanwhile, the flexural strength, tensile strength and modulus can be maintained at a relative high level. The compatibilization mechanism of PTW lied in the chemical interactions occuring between the end group of PAl010 and epoxy groups of PTW during the blending process, and

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编:周其凤
  • 地址:吉林大学南胡校区
  • 邮编:130012
  • 邮箱:cjcu@jlu.edu.cn
  • 电话:0431-88499216
  • 国际标准刊号:ISSN:0251-0790
  • 国内统一刊号:ISSN:22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:50676