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Preparation and characterization of a chitosan-based low-pH-sensitive intelligent corrosion inhibitor
  • ISSN号:2095-9389
  • 期刊名称:《工程科学学报》
  • 时间:0
  • 分类:O629.8[理学—有机化学;理学—化学] TG174.42[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:[1]Corrosion and Protection Center, Key Laboratory for Corrosion and Protection (MOE), University of Science and Technology Beijing, Beijing 100083, China, [2]Baic Motor Corporation, Ltd., Beijing 1 O1300, China
  • 相关基金:Acknowledgements This work is supported by the National Natural Science Foundation of China (No. 51222106) and the Fundamental Research Funds for the Central Universities of China (No. FRF-TP-14-01 ICI).
中文摘要:

chitosan (CS ) 基于 low-pH-sensitive 聪明的腐蚀禁止者被与 benzotriazole (BTA ) 装载 pH 敏感的 hydrogel 准备;pH 敏感的 hydrogel 是由有 glutaraldehyde (GTA ) 的 crosslinking CS 的 synthetized。由 Fourier- 变换的分析红外线(FTIR ) 光谱学证明 Schiff 反应发生了在之间氨基并且醛组。hydrogel 的胀大的能力用一个集体方法被调查,并且比在碱的环境在酸的环境更胀大被观察。装载 BTA 的能力的 hydrogels 是约 0.377 g ?????? 貔 ? 貔 ?$

英文摘要:

A chitosan (CS)-based low-pH-sensitive intelligent corrosion inhibitor was prepared by loading a pH-sensitive hydrogel with benzotriazole (BTA); the pH-sensitive hydrogel was synthetized by crosslinking CS with glutaraldehyde (GTA). Analysis by Fou- tier-transform inflared (FT-IR) spectroscopy showed that Schiff reactions occurred between amino and aldehyde groups. The swelling abil- ity of the hydrogel was investigated using a mass method, and it was observed to swell more in an acidic environment than in an alkaline en- vironment. The hydrogel's loading capacity of BTA was approximately 0.377 g·g ^-1, and its release speed was faster in an acidic environment than in an alkaline environment because of its swelling behavior. The corrosion inhibition ability of the intelligent inhibitor was tested by immersion and electrochemical methods. The results showed that after 4 h of immersion, the polarization resistance (Rp) value of copper with the intelligent inhibitor was approximately twice of that of copper with BTA, indicating that the intelligent inhibitor could effectively prevent copper from corroding.

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期刊信息
  • 《工程科学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国教育部
  • 主办单位:北京科技大学
  • 主编:张欣欣
  • 地址:北京市海淀区学院路30号
  • 邮编:100083
  • 邮箱:xuebaozr@ustb.edu.cn
  • 电话:010-62332875
  • 国际标准刊号:ISSN:2095-9389
  • 国内统一刊号:ISSN:10-1297/TF
  • 邮发代号:82-303
  • 获奖情况:
  • 首届国家期刊奖,第二届全国优秀科技期刊评比一等奖,全国高等学校自然科学学报系统优秀学报评比一等奖,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 日本日本科学技术振兴机构数据库,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:392