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Synthesis of β-cyclodextrin-modified carbon nanocrystals and their fluorescent behavior
  • ISSN号：0251-0790
  • 期刊名称：《高等学校化学学报》
  • 时间：0
  • 分类：O636.12[理学—高分子化学;理学—化学] TB383[一般工业技术—材料科学与工程]
  • 作者机构：[1]Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
  • 相关基金：This paper is dedicated to Professor LIU YouCheng on the occasion of his 90th birthday. This work was supported by the National Basic Research Program of China （2006CB932900） and the National Natural Science Foundation of China （20932004 and 20972077）.
作者： JIANG Qiao ZHANG HengYi LIU Yu[1]
关键词： 纳米晶, 环糊精, 荧光行为, 修饰, 合成, 碳, 透射电子显微镜, 光诱导电子转移, carbon nanocrystals, β-cyclodextrin, supramolecular chemistry, fluorescence
中文摘要：

水溶性的 -cyclodextrin (-CD)-modified 碳 nanocrystals (计算机数值控制) 被计算机数值控制的反应综合了与单音(6-diethylenetriamino-6-deoxy )-- CD (DETA -- CD ) 并且包括地由 1H NMR 描绘了，英尺红外，传播电子显微镜学(TEM ) 并且紫外力。DETA --修改 CD 的计算机数值控制(DETA --CD 计算机数值控制) 是光的，并且量收益是 8.41% 。在 DETA 之间的 photoinduced 电子转移(宠物) 过程 --CD 计算机数值控制并且(ferrocenylmethyl ) trimethylammonium 碘化物(Fc+) 借助于荧光光谱学被调查。

英文摘要：

Water-soluble β-cyclodextrin （β-CD）-modified carbon nanocrystals （CNCs） have been synthesized by the reaction of CNCs with mono（6-diethylenetriamino-6-deoxy）-β-CD （DETA-β-CD） and comprehensively characterized by 1H NMR, FT-IR, transmission electron microscopy （TEM） and UV-Vis. DETA-fl-CD-modified CNCs （DETA-β-CD-CNCs） are luminescent, and the quantum yield is 8.41%. The photoinduced electron transfer （PET） process between DETA-β-CD-CNCs and （ferrocenylmethyl） trimethylammonium iodide （Fc＋） was investigated by means of fluorescence spectroscopy.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊（2011版）
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编：周其凤
  • 地址：吉林大学南胡校区
  • 邮编：130012
  • 邮箱：cjcu@jlu.edu.cn
  • 电话：0431-88499216
  • 国际标准刊号：ISSN：0251-0790
  • 国内统一刊号：ISSN：22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
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  • 被引量:50676