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Synthesis of indenyllanthanide amides:the effective initiators for polymerization of methyl methacrylate
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 时间:0
  • 分类:O631[理学—高分子化学;理学—化学]
  • 作者机构:Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215006, China, China Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (No. 29672026 and 29872031);the Natural Science Foundation of Jiangsu Province;Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sci
中文摘要:

Diisopropylamido bisindenyl lanthanides(C9H7)2LnN(i-Pr)2(Ln=Gd(1),Y(2),Er(3))were successfully synthesized in satisfied yield by the reaction of Ln(N(i-Pr)2)3(THF)with indene in 1:2 molar ratio in toluene.All of the complexes exhibit very high catalytic activity in the polymerization of methyl methacrylate.The resulting polymers have narrow molecular weight distributions and high syndiotacticity.

英文摘要:

Diisopropylamido bisindenyl lanthanides (C9H7)2LnN(i-Pr)2 (Ln=Gd(1), Y(2), Er (3)) were succesfully synthesized in satisfied yield by the reaction of Ln(N(i-Pr)2)3(THF) with indene in 1:2 molar ratio in toluene. AH of the complexes exhibit very high catalytic activity in the polymerization of methyl methacrylate. The resulting polymers have narrow molecular weight distributions and high syndiotacticity.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175