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A novel heteroseneous reaction for generating gaseous nitrous acid
  • ISSN号：1005-281X
  • 期刊名称：《化学进展》
  • 时间：0
  • 分类：O613.61[理学—无机化学;理学—化学]
  • 作者机构：[1]Beijing National Laboratory for Molecular Sciences, and State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China, [2]State Key laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chi- nese Academy of Sciences, Beijing 100029, China
  • 相关基金：Supported by the Knowledge Innovation Program of the Chinese Academy of Sciences （Grant No. KZCX2-YW-205） and Hundred Talents Fund, the 973 Program of Ministry of Science and Technology of China （Grant No. 2006CB403701）, the National Natural Science Foundation of China （Grant Nos. 20577052, 20673123, 20473094, and 20503035）
作者： WANG WeiGang[1], GE MaoFa[1], YAO Li[1], ZENG XiaoQing[1], WANG ZiFa[2]
关键词： 亚硝酸, 气体, 网络技术异构性, 化学结构, MONO, PES-PIMS, DRIFTS
中文摘要：

短命反应标本亚硝酸单音被气体的 HCI 的异构的反应与能比另外的方法产生人的更高的集中的 AgNO2 在煤气的阶段产生。我们在不同控制温度下面在煤气的阶段从产生调查了这个过程到分离，并且由光电子光谱学和光电游离团光谱学(PES-PIMS ) 并且在 situ 的联合在稳固的表面上讨论了 ionlzation 和反应弥漫的反射红外线的 Fourier 变换光谱学(飘移) 。

英文摘要：

The short-lived reactive specimen nitrous acid HONO was generated in the gas phase by the heterogeneous reaction of gaseous HCl with AgNO2 which can generate higher concentration of HONO than other methods. We investigated the process from generation to dissociation in the gas phase under different controlled temperatures, and discussed the ionization and reaction on the solid surface by combination of the photoelectron spectroscopy and photoionization mass spectroscopy （PES-PIMS） and in situ diffuse reflectance infrared Fourier transform spectroscopy （DRIFTS）.

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期刊信息
  • 《化学进展》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学院
  • 主办单位:中国科学院基础研究局 化学部 文献情报中心
  • 主编：
  • 地址：北京中关村四环西路33号
  • 邮编：100080
  • 邮箱：scinfo@mail.las.ac.cn
  • 电话：010-82627757
  • 国际标准刊号：ISSN：1005-281X
  • 国内统一刊号：ISSN：11-3383/O6
  • 邮发代号:82-645
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）
  • 被引量:21655