采用传统固相烧结工艺,结合特殊的气氛控制技术,制备了铌酸钾钠(KNN)基无铅透明陶瓷xBa(Sc0.5Nb0.5)03.(1-x)(K0.5N0.5)NbO3(简写xBSN-(1-x)KNN).并对其微观结构、介电、铁电性能和光学透光率进行了研究.结果表明该体系陶瓷具有准立方钙钛矿结构,没有其他杂相,晶粒大小与可见光波长相当,高度致密,无明显的晶界存在.在x=0.05时,d33最高可达到110pC/N,2Pr达到25.4μC/cm2.同时该材料具有良好的透明性,在可见光范围内,透过率达到54%左右,近红外2500nm处,透过率接近83%,是一种有望取代铅基透明陶瓷的环境友好型无铅透明陶瓷.
Using conventional solid-phase sintering technique combined with a special atmosphere controlling technique, KNN-based lead- free transparent ceramics, xBa(Sc0.5Nb0.5)O3-(1 - x) (K0.5N0.5)NbO3 (xBSN-(1 - x) KNN), are prepared and investigated. Their microstructure, dielectric performance, ferroelectric performance and optical transparency are investigated. The results show that such ceramics are each with a pseudocubic-Perovskite structure, without any other impure phase. Their grain size is comparable to the light wavelength and the grains are highly condensed without evident crystal borders. For x = 0.05, the d33 reaches up to 110 pC/N maximally and the 2Px=25.4 μC/cm2. Moreover, such ceramics are each with an excellent transparency. Their optical transparency reaches about 54%, In the near-infrared wavelength 2500 nm, their optical transparency is near 83%. Such ceramics are a type of environment-friendly lead-free transparent ceramics which may be promising in replacing lead-based transparent ceramics.