中文摘要：

用浸渍法混合负载制备了一种分子筛负载复合氧化物催化剂CuO／Bi2O3／ZSM-5，并探讨了催化剂的制备条件与反应条件对催化甲醛乙炔化生成1，4一丁炔二醇反应的催化活性的影响。实验结果表明，CuO／Bi2O3/ZSM-5催化剂用于甲醛乙炔化反应的适宜的反应条件是：常压、363K，催化剂用量为每50mL甲醛溶液（初始浓度为37％）5g催化剂，乙炔空速0．14～0.16s^-1，反应24h。在此条件下，丁炔二醇得率为89％~92％，选择性为96％左右，副产物丙炔醇得率约为2％。

英文摘要：

The molecule sieve-support complex oxide （CuO/BizO3/ZSM 5） catalyst was prepared by impregna- tion. The effect of preparation and reaction conditions on ethynylation of formaldehyde was investigated. Results show that under the optimum conditions of reaction temperature 363 K, atmospheric pressure, CuO/Biz 03/ZSM-5 catalyst 5 g per 50 mL formaldehyde solution, space velocity of acetylene 0.14-- 0.16s^1, and reaction time 24 h, the yield and selectivity of butynediol could reach 89%--92% and 96%, respectively, and the yield of byproduct propargyl alcohol is about 2%.