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中文摘要：
采用荧光光谱技术,测量了一种卟啉侧链聚合物：卟啉丙烯酸酯-苯乙烯共聚物（P[（por）A-S]）的稳态和瞬态的发光性能。通过将聚合物P[（por）A-S]掺杂到有机玻璃（PMMA）中,研究了链间距离对于P[（por）A-S]发光性能的影响。结果表明：随着聚合物分子浓度增大,即链间距离减小,导致卟啉侧链基团之间的相互间作用增加,使其激发态无辐射跃迁几率增加,聚合物荧光强度减弱,激发态寿命缩短。讨论了上述过程产生的原因。
英文摘要：
The steady-static and transient luminescence in porphyrin side chain polymer P[ （por）A-S] doped in PMMA were studied by using transient and steady-state fluorescence spectroscopic technique. The results show that with the decrease of the interchain distance of P[ （por）A-S ], the interactions of the porphyrins enhance which increase the nonradiating transition. As a result, the luminescence efficiency and＇the lifetime are inversely proportional to the interchain distance of P[ （por）A-S]. We also discuss the origin of the luminescence of P [ （por）A-S] doped in PMMA.
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