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污灌区土壤中多环芳烃的垂直分布及可能来源
  • ISSN号:0250-3301
  • 期刊名称:环境科学
  • 时间:0
  • 页码:-
  • 分类:X53[环境科学与工程—环境工程]
  • 作者机构:[1]中国地质大学(武汉)环境学院,武汉430074
  • 相关基金:国家自然科学基金项目(40830748,40972156)
  • 相关项目:污灌区浅层地下水系统中壬基酚迁移转化规律研究
中文摘要:

用气相色谱-质谱联用(GC/MS)的方法分析太原市小店污灌区9个土壤剖面中16种多环芳烃(PAHs)含量及垂直分布特征.结果表明,小店污灌区表层土(0~10 cm)中PAHs平均含量变化趋势为背景区〈沼泽区〈清灌区〈污灌区;大部分剖面土中PAHs含量随土层深度增加呈减少趋势,PAHs含量变化幅度较大的位置集中在地表以下0~40 cm范围内;高环(4~6环)PAHs大量富集在距地表0~50 cm土壤内,清灌区土壤对4~6环PAHs的富集能力强于污灌区;不同环数PAHs与TOC和砂粒呈正相关关系(rmax=0.791,P=0;rmax=0.882,P=0),与pH呈负相关关系(rmin=-0.1,P=0.702);距地表0~40cm范围内的土壤中PAHs的主要污染来源为小店区煤的燃烧;燃烧产生PAHs的污染途径一是直接沉降至土壤中,二是沉降至水体中,吸附在固体颗粒表面,随着灌溉污水流动而在土壤中大量富集.

英文摘要:

Nine profile soil samples were collected from Xiaodian sewage irrigation area,Taiyuan city,China.The concentrations of 16 polycyclic aromatic hydrocarbons(PAHs) were analyzed by gas chromatography equipped with a mass spectrometry detector(GC/MS).The rank order of the average concentrations of PAHs in the 0-10 cm upper soil layer was background areaswamp areagroundwater irrigation area sewage irrigation area.The concentrations of PAHs in most profile soils decreased with the increase of depth,and the PAHs were mainly accumulated in the surface soil layer(0-40 cm).4-6 rings of PAHs were mainly accumulated in the 0-50 cm soil layer,and the accumulation capacity in groundwater-irrigation area was better than that in sewage irrigation area.The correlation between different rings of PAHs and TOC was positive(rmax=0.791,P=0),and the same situation was found for PAHs and sand(rmax=0.882,P=0).The correlation between PAHs and pH was negative(rmin=-0.1,P=0.702).The main source of PAHs in the surface soil layer(0-40 cm) of study area was coal combustion.There were two pollution ways of PAHs in soil,one was settled into soil directly,the other was first settled into water and absorbed on the surface of solid particles,and then got enrichment in soil as irrigation water flew.

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期刊信息
  • 《环境科学》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:赵进才
  • 地址:北京市2871信箱(海淀区双清路18号)
  • 邮编:100085
  • 邮箱:hjkx@rcees.ac.cn
  • 电话:010-62941102 62849343
  • 国际标准刊号:ISSN:0250-3301
  • 国内统一刊号:ISSN:11-1895/X
  • 邮发代号:2-821
  • 获奖情况:
  • 在全国第一届和第二届优秀科技期刊评比中分别荣获...,二次荣获中国科学院优秀期刊评比一等奖,荣获中国期刊方阵双奖期刊荣誉
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国生物医学检索系统,美国剑桥科学文摘,美国生物科学数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:69962