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钙钛矿太阳电池的工作机理及性能的主要影响因素
  • ISSN号:0251-0790
  • 期刊名称:《高等学校化学学报》
  • 时间:0
  • 分类:O649.4[理学—物理化学;理学—化学]
  • 作者机构:[1]国家纳米科学中心,北京100190
  • 相关基金:中国科学院“百人计划”和国家自然科学基金(批准号:21374025,U1401244)资助;感谢关国国家可再生能源实验室提供图1.
中文摘要:

本文综合评述了钙钛矿太阳电池的重要研究成果,解释了其工作机理并总结了影响电池性能的关键因素:钙钛矿化学组成、结晶与形貌、传输层、电极和体异质结等.对钙钛矿太阳电池的未来发展进行了展望.

英文摘要:

Hybrid organic-inorganic perovskites were first introduced to photovoltaic community in 2009. In subsequent years,the power conversion efficiency has increased from 3.8% to ~ 20%,leaving dye-sensitized solar cells and bulk-heterojunction solar cells far behind. "Perovskite"is a crystal possessing the same crystal structure as calcium titanate,namely,ABX3. Perovskites have unique properties,like broad absorption spectra,high absorption coefficient,ambipolar charge transport,long exciton lifetime and very low binding energy of exciton. Currently,the architecture of perovskite solar cells has been simplified from meso-structured solar cells to planar-heterojunction solar cells,getting closer to the low-cost,high-efficiency target for practical application. Many innovative researches are pushing the application of this new photovoltaic material to the climax. This review summarizes the working mechanism of perovskite solar cells and expounds several key factors affecting device performance,i.e. components,crystallization and morphology,transport layers,electrode materials and planted bulk-heterojunction. However,we should note that perovskites have some drawbacks impeding its commercialization. Perovskites are sensitive to oxygen and water vapor,making the solar cells unstable in the ambient; it is challenging to prepare large films because the morphology of perovskite film is difficult to control; the use of the toxic metal,lead,will also undermine the credit earned by their outstanding photovoltaic performance. It is very important for us to understand those mechanism and factors affecting device performance,and to find approaches to deal with instability,toxicity,and bad morphology.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编:周其凤
  • 地址:吉林大学南胡校区
  • 邮编:130012
  • 邮箱:cjcu@jlu.edu.cn
  • 电话:0431-88499216
  • 国际标准刊号:ISSN:0251-0790
  • 国内统一刊号:ISSN:22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:50676