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Relationship between Microstructure Evolution and the Luminescent Properties of Eu3 +-doped Yttrium Aluminum Garnet and Y2O3 Nano-powders
  • ISSN号:1005-0302
  • 期刊名称:《材料科学技术学报:英文版》
  • 时间:0
  • 分类:TQ174.758[化学工程—陶瓷工业;化学工程—硅酸盐工业] TN248.13[电子电信—物理电子学]
  • 作者机构:[1]Institute of Modern Physics, Xiangtan University, Xiangtan 411105, China, [2]Department of Physics, Hunan University of Science and Technology, Xiangtan 411201, China
  • 相关基金:This work was supported by the National Natural Scientific Foundation of China (No. 10874144) and the Scientific Foundation of Education, Department of Hunan Province, China (No. 06C818).
中文摘要:

<正>Eu3+-doped yttrium aluminum garnet(YAG) and Y2O3 composite phase nanoparticles were synthesized using a modified hydrothermal method.Sintering was performed at 800℃,which is considerably lower than the sintering temperature used in the conventional method.Y3+ in YAG and Y2O3 was partially substituted with Na+ by adding NaNO3 into the solution during sample synthesis.The microstructures and phase transformation process were characterized through X-ray diffraction,scanning electron microscopy,and transmission electron microscopy.The obtained results verified that the addition of Na+ promoted crystallinity and grain growth of the three phases,namely,Y2O3,Y4AI2O9,and Y3AI5O12.Highly efficient luminescence properties excited by 254 and 365 nm ultraviolet were achieved.In conclusion,the remarkable enhancement of the luminescence intensity with the addition of Na+ should be attributed to grain growth and improvement of crystallinity.

英文摘要:

Eu3+-doped yttrium aluminum garnet (YAG) and Y2O3 composite phase nanoparticles were synthesized using a modified hydrothermal method. Sintering was performed at 800 ℃, which is considerably lower than the sintering temperature used in the conventional method, y3+ in YAG and Y2O3 was partially substituted with Na+ by adding NaNO3 into the solution during sample synthesis. The microstructures and phase transformation process were characterized through X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The obtained results verified that the addition of Na+ promoted crystallinity and grain growth of the three phases, namely, Y2O3, Y4Al2O9, and Y3Al5O12. Highly efficient luminescence properties excited by 254 and 365 nm ultraviolet were achieved. In conclusion, the remarkable enhancement of the luminescence intensity with the addition of Na+ should be attributed to grain growth and improvement of crystallinity.

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期刊信息
  • 《材料科学技术学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国金属学会
  • 主编:
  • 地址:中国沈阳文化路72号
  • 邮编:110016
  • 邮箱:
  • 电话:024-83978208
  • 国际标准刊号:ISSN:1005-0302
  • 国内统一刊号:ISSN:21-1315/TG
  • 邮发代号:
  • 获奖情况:
  • 国家“双百”期刊
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  • 被引量:474