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太湖水体中稀土元素地球化学特征
  • 期刊名称:中国稀土学报
  • 时间:0
  • 页码:233-238
  • 语言:中文
  • 分类:X142[环境科学与工程—环境科学] P592[天文地球—地球化学;天文地球—地质学]
  • 作者机构:[1]天津师范大学水环境与水资源重点实验室,天津300387, [2]中国科学院地球化学研究所环境地球化学国家重点实验室,贵州贵阳550002
  • 相关基金:国家自然科学基金(40803002 40773011); 天津市应用基础及前沿技术研究计划(09JCYBJC07900 09JCZDJC25900 10JCZDJC24800); 天津市高校科技发展基金项目(20070711)资助
  • 相关项目:天津滨海地区海(咸)水入侵的锶同位素示踪研究
中文摘要:

以中国第三大淡水湖泊太湖为研究对象,通过液-液萃取、连续提取法以及ICP-MS测试技术对太湖水体中溶解态和悬浮物中的稀土进行分析。结果表明:太湖水体中溶解态稀土含量较低,由于湖水的混合作用整个西太湖水体中稀土元素含量比较相近,东太湖水体由于自净化作用含量低于西太湖。由于颗粒物表层胶体的吸附作用,溶解态稀土呈现出重稀土富集现象。悬浮物AEC态可能由于富含铁的有机胶体、磷酸根络合和富含铁锰次生矿物相等的作用,呈现出中稀土富集。水体中溶解态稀土几乎全部是以有机络合物的形式存在;悬浮物是稀土元素的主要载体,且残渣态〉AEC态〉溶解态。

英文摘要:

The concentrations of the dissolved and particulate rare earth elements were determined in waters of the Taihu Lake,the third largest freshwater lake of China,by using the inductively coupled plasma mass spectrometry(ICP-MS) after preconcentration with solvent extraction and back-extraction techniques and sequential extraction procedures.The result showed that the concentrations of dissolved rare earth in the Taihu Lake were relatively low.Moreover,dissolved REE had nearly similar contents in the West Taihu Lake due to sufficient water mixing.And in the East Taihu Lake,the concentrations of dissolved REE were lower than that of the West Taihu Lake because of particulate scavenging.Due to the sorption process by colloids and particles,the shale-normalized dissolved REEs of the Taihu Lake had HREE-enriched composition.The shale-normalized patterns of REE in AEC of the suspended particle matter showed MREE enrichment probably due to sorption of Fe-organic colloids and secondary minerals and phosphate complexation in the water.Almost all dissolved rare earth in the water were present as Ln-HM.The suspended particulate matter was the major media of rare earth elements and with the decreasing order residual,AEC and dissolved.

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