Enantioselective and a-Regioselective Allylic Amination of Morita-Baylis-Hillman Acetates with Simple Aromatic Amines Catalyzed by Planarly Chiral Ligand/Palladium Catalyst
- ISSN号:1001-604X
- 期刊名称:《中国化学:英文版》
- 时间:0
- 分类:TQ925.6[轻工技术与工程—发酵工程;化学工程] O621.3[理学—有机化学;理学—化学]
- 作者机构:[1]Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China, [2]Graduate School of Chinese Academy of Sciences, Beij'ing 100049, China
- 相关基金:Acknowledgement We are grateful to National Natural Science Founda- tion of China, Ministry of Science and Technology (No. 2010CB833300) and the Chinese Academy of Sciences for the financial support.
关键词:
对映体选择性, 区域选择性, 钯催化剂, 手性配体, 烯丙基, 芳香胺, 胺化, 醋酸盐, asymmetric allylic amination, Morita-Baylis-Hillman adducts, aromatic amines, palladium catalysis,diphosphine ligands
中文摘要:
E-mail: lliu@icca.ac.cn