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煤气化废水处理中双侧线汽提塔的应用
  • ISSN号:1005-9954
  • 期刊名称:化学工程
  • 时间:2013.3.15
  • 页码:63-66+74
  • 分类:TQ028[化学工程]
  • 作者机构:[1]华南理工大学化学与化工学院,广东广州510640
  • 相关基金:国家自然科学基金资助项目(21136003);广州市珠江科技新星计划项目(2011J2200056)
  • 相关项目:颗粒化学品制备过程的产品质量控制
中文摘要:

针对具有较高pH值的煤气化废水,采用酸性气饱和煤气化废水能降低废水pH值,改善萃取条件后进行萃取。但萃取后的萃余液中存在大量的酸性气、氨和萃取剂。为了回收氨和萃取剂,并脱除酸性气,在原有工作基础上,采用双侧线汽提塔处理萃余液,该塔塔顶分离酸性气,上侧线回收萃取剂,下侧线回收氨。文中是这一建议流程的后续研究工作。通过流程模拟,对影响双侧线汽提塔分离效果的因素,如热进料位置和塔顶采出量、冷热进料比和冷进料温度、上侧线采出位置和采出量、下侧线采出位置和采出量等进行模拟优化。模拟结果显示:双侧线汽提塔可满足塔釜水净化的要求,且有效地分离酸性气、氨和萃取剂,最大程度地回收氨和萃取剂,初步证明了双侧线汽提塔工艺的可行性。

英文摘要:

In order to improve the extraction condition of coal-gasification wastewater with a higher pH value, acid gas saturation was used to reduce the pH value. However, there were lots of sour gas, ammonia and extractant in the raffinate after extraction. For recycling ammonia and extractant, meanwhile removing acid gas, the process of double side-draw stripper was employed on that basis of existing work. The basic steps involved in this process are separation of acid gas from the tower top, recycling of extractant from the upper side-draw, and ammonia from the down side-draw. The follow-up of this proposal process was studied. The factors that affect the separation of double side-draw stripper, such as hot feed location, tower top distillation, cold/hot feed ratio, cold feed temperature, location and production of the upper side-draw, location and production of the down side-draw were optimized by process simulation. The results show that the process of double side-draw stripper can not only meet the waterpurification requirements of tower kettle, but also effectively separate the acid gas, ammonia and extractant. Besides, the process can achieve the maximum recovery degree of ammonia and extractant. The process feasibility of double side-draw stripper was preliminarily evidenced.

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期刊信息
  • 《化学工程》
  • 中国科技核心期刊
  • 主管单位:中国华陆工程科技有限责任公司
  • 主办单位:中国华陆工程科技有限责任公司
  • 主编:程惠亭
  • 地址:陕西省西安市高新技术产业开发区唐延南路7号 华陆大厦
  • 邮编:710065
  • 邮箱:chem_eng@chinahualueng.com
  • 电话:029-87989701 27988823/4/6
  • 国际标准刊号:ISSN:1005-9954
  • 国内统一刊号:ISSN:61-1136/TQ
  • 邮发代号:52-52
  • 获奖情况:
  • 第六届全国石油和化工行业优秀期刊一等奖,历届陕西省科学技术类优秀期刊,首届《CAJ-CD规范》执行优秀期刊奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),波兰哥白尼索引,荷兰文摘与引文数据库,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:11323