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Synthesis of diamonds in Fe-C systems using nitrogen and hydrogen co-doped impurities under HPHT
  • ISSN号:1674-1056
  • 期刊名称:《中国物理B:英文版》
  • 时间:0
  • 分类:O474[理学—半导体物理;理学—物理] TS933.21[轻工技术与工程]
  • 作者机构:[1]College of Science, Tianjin University of Technology, Tianjin 300384, China, [2]College of Physics and Materials Science, Tianjin Normal University Tianjin 300387, China, [3]State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China
  • 相关基金:Project supported by the National Natural Science Foundation of China(Grant Nos.11504267,11504269,and 51172089); the Open Project of State Key Laboratory of Superhard Materials,Jilin University,China(Grant No.201504); the Doctoral Fund of Tianjin Normal University,China(Grant No.52XB1518).
中文摘要:

在这研究,我们与 C 3 N 6 在在范围 5.0-6.5 GPa 和 1400-1700 的温度的压力的 H 6 添加剂

英文摘要:

In this study, we investigate the effect of nitrogen and hydrogen impurities on colors, morphologies, impurity structures and synthesis conditions of diamond crystals in Fe–C systems with C3N6H6 additives at pressures in the range 5.0–6.5 GPa and temperatures of 1400–1700℃ in detail. Our results reveal that the octahedron diamond nucleation in a Fe–C system is evidently inhibited by co-doped N–H elements, thereby resulting in the increase of minimum pressure and temperature of diamond synthesis by spontaneous nucleation. The octahedron diamond crystals synthesized from a pure Fe–C system are colorless, while they become green in the system with C3N6H6 additive. The surface defects of diamond will deteriorate when the nitrogen and hydrogen atoms simultaneously incorporate in the diamond growth environment in the Fe–C system. We believe that this study will provide some important information and be beneficial for the deep understanding of the crystallization of diamonds from different component systems.

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期刊信息
  • 《中国物理B:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会和中国科学院物理研究所
  • 主编:欧阳钟灿
  • 地址:北京 中关村 中国科学院物理研究所内
  • 邮编:100080
  • 邮箱:
  • 电话:010-82649026 82649519
  • 国际标准刊号:ISSN:1674-1056
  • 国内统一刊号:ISSN:11-5639/O4
  • 邮发代号:
  • 获奖情况:
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  • 被引量:406