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改性凹凸棒土及粉末活性炭助凝聚硅硫酸铝消除微污染水中有机氯
  • ISSN号:0253-2468
  • 期刊名称:《环境科学学报》
  • 时间:0
  • 分类:X703[环境科学与工程—环境工程]
  • 作者机构:[1]兰州交通大学环境与市政工程学院,兰州730070
  • 相关基金:国家自然科学基金(No.21277065);教育部长江学者和创新团队项目(No.IRT0966);甘肃省自然科学基金(No.1107RJYA055)
中文摘要:

以硅酸钠和硫酸铝为原料制备了聚硅硫酸铝絮凝剂(PASS),采用强化混凝的处理方法,对微污染水中有机氯(OCPs)的消除进行了研究.同时,考察了混凝剂投加量、pH值、原水浊度、粉末活性炭和改性凹凸棒土助凝剂等因素对OCPs消除效果的影响.结果表明:PASS投加量为5 mg·L^-1时,OCPs的去除率可以达到57%-87%,浊度去除率可以达到99.1%,其效果好于聚合氯化铝(PAC);PASS混凝处理OCPs的最佳pH值范围是6-7;OCPs的去除与浊度的去除具有显著相关性,原水浊度的大小会影响OCPs的去除,低浊条件下OCPs和浊度的去除率明显低于中浊和高浊条件;粉末活性炭和改性凹凸棒土作为助凝剂与PASS复配均可显著提高OCPs的去除率,分别达到78%-100%和72%-95%.相较而言,凹凸棒土储量丰富,廉价易得,因此,以改性凹凸棒土替代粉末活性炭更有优势.

英文摘要:

Polysilicate aluminium sulphate (PASS) flocculant was prepared by sodium silicate and aluminum sulphate. The elimination of organochlorine pesticides (OCPs) from micro-polluted water by coagulation with PASS was studied. The effects of the dosage of coagulant, pH values, initial turbidity as well as the addition of assistant coagulant on the elimination efficiency of OCPs were determined respectively. The result showed that under the dosage of 5 mg·L^-1 PASS, the removal rates of OCPs and turbidity reached 57%-87% and 99.1%, respectively, much higher compared with polyaluminium chloride (PAC). The best range of pH values was 6-7 for OCPs elimination. The removal rates of OCPs were relevant to the turbidity, and increased with the increasing in initial turbidity. Modified attapulgite and powder activated carbon used as assistant coagulants significantly enhanced the coagulation, with the removal rates of OCPs of 78%-100% by powder activated carbon and 72%-95% by modified attapulgite, respectively. As attapulgite is abundant, cheap and easy to acquire, it is more suitable to be used as the assistant coagulant compared to powder activated carbon.

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期刊信息
  • 《环境科学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:汤鸿霄
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjkxxb@rcees.ac.cn
  • 电话:010-62941073
  • 国际标准刊号:ISSN:0253-2468
  • 国内统一刊号:ISSN:11-1843/X
  • 邮发代号:82-625
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰地学数据库,荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:56074