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采用Ti/PbO2阳极氧化进行污泥预处理的研究
  • ISSN号:0253-2468
  • 期刊名称:《环境科学学报》
  • 时间:0
  • 分类:X703[环境科学与工程—环境工程]
  • 作者机构:[1]深圳大学化学与环境工程学院,深圳518060, [2]环保部华南环境科学研究所,广州510655, [3]深圳大学物理与能源学院,深圳518060
  • 相关基金:国家自然科学基金(No.21547011,21307036,11275130);广东省自然科学基金(No.2014A030313761);深圳市科技计划基础研究项目(No.JCYJ20150324141711622,JCYJ20150529164656097)
中文摘要:

提高市政污泥脱水性能是当前污泥预处理中的热点和难点.本文以毛细吸水时间(CST)作为衡量污泥预处理中脱水性能的指标,选用钛/二氧化铅网状极板为阴、阳电极,研究了电解电压、极板间距、电解质种类及电解质投加量等因素对电化学预处理市政污泥的影响.结果表明,电压对污泥脱水性能影响较大,在电压为20 V、极板间距为2 cm、电解质为0.6 g Na Cl的条件下,电化学处理市政污泥20 min效果最佳,污泥的CST下降率在90%以上.进一步探究表明,电解过程中污泥菌胶团结构首先被破坏,释放大量结合水,且菌胶团内的蛋白质和多聚糖释放到上清液中,二者浓度先升高;随后二者部分氧化分解,浓度降低,从而有效提高市政污泥脱水性能.

英文摘要:

It is a hotresearch topic for improving the dewaterability of municipal sludge in pretreatment. In this study,Ti/PbO_2 mesh plate electrodes were explored as the anode and cathode to treat municipal sludge. The capillary suction time( CST) was used to quantify the sludge dewaterability. The effects of the operating parameters on sludge pretreatment performance were investigated including electrolytic voltage,electrode gap,electrolyte species,and the dosage of electrolyte. The results show that electrolytic voltage was of significance to the sludge dewaterability. The optimal parameters were 20 V of voltage,2 cm of electrode distance,0. 6 g Na Cl,and 20 min of electrolysis time. Under these optimal parameters,the CST of sludge has decreased significantly over 90%. Further exploration showed that the sludge structure was destroyed firstly with the release of a large number of bound water. During the initial stage of electrolysis,relatively high amount of proteins and polysaccharide were also released into supernatant. Then,their concentration decreased since part of proteins and polysaccharide was further decomposed by electrooxidation. Afterwards, it was effectively improved for the dewaterability of the municipal sludge.

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期刊信息
  • 《环境科学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:汤鸿霄
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjkxxb@rcees.ac.cn
  • 电话:010-62941073
  • 国际标准刊号:ISSN:0253-2468
  • 国内统一刊号:ISSN:11-1843/X
  • 邮发代号:82-625
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰地学数据库,荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:56074