采用座滴法研究了PdNi—Cr-V合金钎料对SiC陶瓷的润湿性.设计的PdNi-(16-22)Cr-(7—21)V—Si—B(质量分数)钎料可用于SiC的连接,使用急冷态箔状钎料,在1190℃/10min的连接条件下得到的接头室温三点抗弯强度平均值为84.6MPa.微观分析表明,在靠近SiC的界面反应层中,主要是Pd和Ni优先与SiC反应生成相应的Pd-Si相、Ni—Si相和石墨;离SiC稍远的接头区域,主要是Cr和V与C和Si发生反应,生成Cr(v)-C,Cr(V)-Si,Cr(V)5Si3C等相;钎缝中心区的基体由Pd-Si,Ni-Si和V—Si相组成,其上弥散分布着块状碳化物V2C和Cr23C6.
Wettability of PdNi-Cr-V alloy on SiC was studied with the sessile drop method. The newly developed PdNi-(16-22)Cr-(7-21)V-Si-B (mass fraction,%) brazing filler could be used for joining SiC. The room temperature three-point bend strength of the SiC/SiC joints brazed with rapidly solidified brazing foils at 1190 ℃ for 10 min is 84.6 MPa. In the interfacial layer near to SiC, elements Pd and Ni preferentially diffused into SiC and resulted in the reaction products of Pd-Si phase, Ni-Si phase and graphite. In the reaction zone further away from the SiC, mainly elements Cr and V in the brazing filler participated in the interface reaction, and formed Cr(V)-C, Cr(V)-Si, Cr(V)sSi3C. In the central part of the joint, the matrix was composed of Pd-Si, Ni-Si and V-Si phases, on which some blocky carbides V2C, Cr23C6 distributed dispersively.