将6H-SiC和a-A1203以质量比7:3混合,添加质量分数0-10%的MgO-CaO作为烧结助剂,球磨后的粉体压制成生坯,在1200℃预氧化1h后在氢气氛下常压烧结1h制备A1203.SiC复相材料。研究了烧成温度和MgO-CaO含量对该复相材料烧结性能和相组成的影响。结果表明:1500℃下,随着烧结助剂含量的增加,烧结致密性明显提高,当烧结助剂质量分数为10%时,显气孔率降至0.1%。预氧化时,添加烧结助剂MgO.CaO,方石英和甜A1203与之反应,生成CaAl2Si2O8和Mg2Al4Si5O18,促进6H-SiC的进一步氧化。烧成过程中,CaAl2Si2O8和MgAl2O4溶解生成玻璃相促进烧结,同时a-Al2O3从玻璃相中析出,1500℃烧结试样所含物相为6H-SiC和a-Al2O3。
6H-SiC and a-Al2O3 powders mixed as raw materials (mass ratio additives, Al2O3-SiC composites were prepared by pressureless sintering for 1 h body being preoxidized for 1 h at 1 200 ℃. The effects of sintering temperature properties and phase composition were investigated. Result shows that when 7:3), adding MgO and CaO as sintering in hydrogen atmosphere after the green and MgO-CaO content on the sintering sintering temperature is 1 500 ℃, the compactness improves obviously with the increase of content of sintering addictives. With w(MgO-CaO) of 10 % added, the sample's apparent porosity is 0.1%. When the green body is preoxidized, CaAl2Si2O8 and Mg2A14Si5O18 are generated by the reaction of MgO-CaO with a-A1203, SiO2. During the sintering process, CaAl2Si2O8 and MgAl2O4 form liquid glass phase which promotes sintering and deposits a-Al2O3. The sample's crystal phases are 6H-SiC and a-A1203 at I 500 ℃.