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In situ Surface Functionalization of Hydrophilic Silica Nanoparticles via Flame Spray Process
  • ISSN号:1005-0302
  • 期刊名称:Journal of Materials Science & Technology
  • 时间:2015.9
  • 页码:901-906
  • 分类:TQ63[化学工程—精细化工] TM273[电气工程—电工理论与新技术;一般工业技术—材料科学与工程]
  • 作者机构:Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
  • 相关基金:Acknowledgments This work was supported by the National Natural Science Foundation of China (Nos. 51173043, 21236003, and 21322607), the Basic Research Program of Shanghai (Nos. 13JC1408100 and 15JC1401300), the Key Scientific and Technological Program of Shanghai (No. 14521100800), and the Fundamental Research Funds for the Central Universities.
  • 相关项目:基于微碳纤布/碳纳米管/碳气凝胶三维网络结构的柔性导电材料的制备、结构与性能
中文摘要:

透明擦伤的一种新类型在原处包括的抵抗涂层修改了 SiO 2( 在火焰水花热分解(FSP ) 的 g-SiO 2) 过程被准备。在涂层的 g-SiO 2 的最大的内容是 15 wt% ,它比传统的湿化学线路修改的 SiO 2 的高(l-SiO 2, 仅仅 10 wt%) 。传播电子显微镜学的结果证明了在原处,表面修改了粒子驱散很好与的 g-SiO 2 更小在最后的涂层聚结,它比经由湿化学线路修改的粒子好一些。可见轻发射度和薄雾测试被介绍描绘这些电影的光质量。所有涂层与上面的可见轻发射度是高度透明的 80% ,特别为包含比 l-SiO 展出了稍微更高可见的轻发射度的 g-SiO 2, 的涂层, 2 嵌入一个。与 15 wt% g-SiO 2 合并的涂层的薄雾价值是 1.85% ,甚至与 5 wt% l-SiO 2(2.09% 的薄雾价值) 比涂层降低,显示 g-SiO 的好一些的清澈 2 。g-SiO 2 的优秀光性质充满了涂层被归因于粒子的好分散和分发。Nano 缩进和 nano 擦伤测试被进行在 nano 规模上调查涂层的擦伤抵抗。涂层的表面坚硬上升了 18% 和 14% ,并且分别地,平均磨擦系数由于 10 wt% g-SiO 2 和 l-SiO 2 的增加与整洁的上衣相比在 15% 和 11% 减少了。有 15 wt% g-SiO 2 的涂层的铅笔坚硬为整洁的涂层从 2B 增加了到 2H。然而,有 10 wt% l-SiO 2 的涂层的铅笔坚硬仅仅是 H。结果证明嵌入的涂层更高展出了的 g-SiO 2 抓抵抗和更好光的性质。

英文摘要:

A new type of transparent scratch resistant coatings including in-situ modified SiO2 (g-SiO2) in flame spray pyrolysis (FSP) process was prepared. The maximum content of g-SiO2 in the coating was 15 wt%, which is higher than that of SiO2 modified by traditional wet chemical route (I-SiO2, only 10 wt%). The results of transmission electron microscopy have demonstrated that in-situ surface modified g-SiO2 particles dispersed well with smaller agglomerates in the final coating, which was much better than the particles modified via wet chemical route. Visible light transmittance and haze tests were introduced to characterize the optical quality of the films. All coatings were highly transparent with the visible light transmittance of above 80%, especially for coatings containing g-SiO2, which exhibited slightly higher visible light transmittance than l-SiO2 embedded one. The haze value of coatings incorporated with 15 wt% g-SiO2 was 1.85%, even lower than the coating with 5 wt% I-SiO2 (haze value of 2.09%), indicating much better clarity of g-SiO2. The excellent optical property of g-SiO2 filled coatings was attributed to the good dispersion and distribution of particles. Nano-indention and nano-scratch tests were con- ducted to investigate the scratch resistance of coatings on nano-scale. The surface hardness of the coatings rose by 18% and 14%, and the average friction coefficient decreased by 15% and 11%, respectively, compared to the neat coat due to the addition of 10 wt% g-SiO2 and I-SiO2. The pencil hardness of the coating with 15 wt% g-SiO2 increased from 2B for the neat coating to 2H. However, the pencil hardness of coating with 10 wt% I-SiO2 was only H. The results showed that the g-SiO2 embedded coatings exhibited higher scratch resistance and better optical properties.

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期刊信息
  • 《材料科学技术学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国金属学会
  • 主编:
  • 地址:中国沈阳文化路72号
  • 邮编:110016
  • 邮箱:
  • 电话:024-83978208
  • 国际标准刊号:ISSN:1005-0302
  • 国内统一刊号:ISSN:21-1315/TG
  • 邮发代号:
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  • 国家“双百”期刊
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  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊
  • 被引量:474