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反电荷氨基硅/羧基硅共混乳液的膜形貌与应用性能
  • ISSN号:1005-023X
  • 期刊名称:《材料导报》
  • 时间:0
  • 分类:TQ460.4[化学工程—制药化工]
  • 作者机构:[1]陕西科技大学教育部轻化工助剂化学与技术重点实验室,西安710021
  • 相关基金:国家自然科学基金项目(50373025);教育部博士点基金项目(200807080002);陕西省教育厅重点项目(09Js060);陕西科技大学研究生创新基金
中文摘要:

以质量分数为25%的阳离子N-β氨乙基-γ-氨丙基聚二甲基硅氧烷微乳(ASE)和阴离子羧烃基聚硅氧烷微乳(CSE)为原料,经水相静电自组装、团聚形成反电荷ASE/CSE共混乳液。以单晶硅作载膜基质,采用静态浸渍法将ASE/CSE附着在基质表面使之成膜,然后用原子力显微镜(AFM)、电脑测控柔软度仪等仪器对ASE/CSE的成膜形貌及应用性能进行研究。结果表明,ASE/CSE具有良好的成膜性能,可在单晶硅基质表面成膜,与单组分硅乳成膜形貌明显不同。在单晶硅表面,ASE/CSE所成的复合硅膜表面很粗糙,平均厚度达12.45nm,存在众多岛屿。共混硅乳ASE/CSE整理棉织物的柔软性能较之空白织物明显提升,并赋予织物特殊的油滑手感。

英文摘要:

Using the cationic N-β-aminoethyl-T-aminopropyl polysiloxane microemulsion(ASE) and the anionic carboxyl-containing polysiloxane microemulsion(CSE) as experimental materials, which microemulsion mass concentration is 25%. ASE and CSE are mixed together to self-assemble or aggregate via electrostatic interaction to form counter charged microemulsion compound ASE/CSE. With the silicon wafers as the film forming substrate, ASE/CSE is anchored on the substrate surface through static-dipping method. The film morphology and application properties of the ASE/CSE film self-assembled on silicon wafer are studied and investigated by atomic force microscope(AFM) and softness instrument. Experimental results indicate that ASE/CSE takes on a good form-film property, which has can be adsorbed onto the silicon wafer surface to fabricate a film. However, its film morphology is widely different from the single microemulsion. The ASE/CSE film on the silicon wafer shows a rough surface, which has many islands on its surface, and the average thickness reaches 12.45nm. The softness of cotton fabrics treated by ASE/CSE increase obviously compared with untreated cotton fabrics. Meanwhile, the cotton fabrics acquire particular oily and smooth tactile handle.

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期刊信息
  • 《材料导报:纳米与新材料专辑》
  • 主管单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主办单位:重庆西南信息有限公司(原科技部西南信息中心)
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  • 地址:重庆市渝北区洪湖西路18号
  • 邮编:401121
  • 邮箱:matreved@163.com
  • 电话:023-67398525
  • 国际标准刊号:ISSN:1005-023X
  • 国内统一刊号:ISSN:50-1078/TB
  • 邮发代号:
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  • 被引量:3397