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Degradation of acephate using combined ultrasonic and ozonation method
  • ISSN号:1000-310X
  • 期刊名称:《应用声学》
  • 时间:0
  • 分类:O426[理学—声学;理学—物理] X791.03[环境科学与工程—环境工程]
  • 作者机构:[1]Changzhou Key Laboratory of Sensor Networks and Environmental Sensing, Hohai University, Changzhou 213022, PR China, [2]Nanjing Institute of Electronic Technology, Nanjing 210039, PR China, [3]College of Petrochemical Engineering, Changzhou University, Changzhou 213164, PR China, [4]Changzhou Xinlinian Ultrasonic Equipment Co., Ltd., Changzhou 213104, PR China
  • 相关基金:This work was supported by the National Natural Science Foundation of China (Grants No. 11274092, 11274091, and 11304026), the Jiangsu Graduate Education Reform Research and Practice Project in 2009 (Grant No. 22), and the Fundamental Research Fund for the Central Universities (Grant No. 14B10128). Acknowledgements We gratefully acknowledge Professor Cai-hua Ni and Dr. Bing-yan Chen for their technical support and also Wen Wen, Ying Gao, and Cheng Yin for their advice and discussion.
中文摘要:

在水的答案的 acephate 的降级被调查与超声并且两个的 ozonation 方法,以及联合。一台试验性的设备被设计,象超声的力量,温度,和煤气的流动那样的操作参数评价严格地在经常的层次被控制。超声的波浪的频率是 160kHz。紫外可见(紫外力) 分光镜并且拉曼分光镜的技术在实验被使用。紫外力的分光镜的结果证明 ultrasonication 和 ozonation 在联合系统有 synergistic 效果。在解决方案以后的从 60.6% ~ 87.6% 的 acephate 增加的降级效率被 160kHz 照耀为在 ozonation 的 60min 的超声的波浪进程,和它比和与联合方法是更高的分开超声并且 ozonation 方法。拉曼系列研究证明经由联合 ultrasonic/ozonation 方法的那降级比光催化更彻底。氮原子的 oxidability 在超声的波浪下面被支持。无机的离子和降级小径的变化在这研究在降级过程期间被调查。大多数最后的产品对环境无害。

英文摘要:

The degradation of acephate in aqueous solutions was investigated with the ultrasonic and ozonation methods, as well as a combination of both. An experimental facility was designed and operation parameters such as the ultrasonic power, temperature, and gas flow rate were strictly controlled at constant levels. The frequency of the ultrasonic wave was 160 kHz. The ultraviolet-visible (UV-Vis) spectroscopic and Raman spectroscopic techniques were used in the experiment. The UV-Vis spectroscopic results show that ultrasonication and ozonation have a syn- ergistic effect in the combined system. The degradation efficiency of acephate increases from 60.6% to 87.6% after the solution is irradiated by a 160 kHz ultrasonic wave for 60 min in the ozonation process, and it is higher with the combined method than the sum of the separated ultrasonic and ozonation methods. Raman spectra studies show that degradation via the combined ultrasonic/ozonation method is more thorough than photocatalysis. The oxidability of nitrogen atoms is promoted under ultrasonic waves. Changes of the inorganic ions and degradation pathway during the degradation process were investigated in this study. Most final products are innocuous to the environment.

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期刊信息
  • 《应用声学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院声学研究所
  • 主编:王秀明
  • 地址:北京市海淀区北四环西路21号
  • 邮编:100190
  • 邮箱:yysx@mail.ioa.ac.cn
  • 电话:010-82547761
  • 国际标准刊号:ISSN:1000-310X
  • 国内统一刊号:ISSN:11-2121/O4
  • 邮发代号:2-561
  • 获奖情况:
  • 中国自然科学核心期刊,中国科技论文统计用刊,中国科学引文数据库来源期刊
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  • 被引量:4544