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Lithium-assisted exfoliation of pristine graphite for few-layer graphene nanosheets
  • ISSN号:1998-0124
  • 期刊名称:Nano Research
  • 时间:2015
  • 页码:801-807
  • 分类:TQ564[化学工程—炸药化工] TM911.4[电气工程—电力电子与电力传动]
  • 作者机构:[1]MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, Xi'an, 710049, China, [2]Electronic Materials Research Laboratory, International Center for Dielectric Research, Xi'an Jiaotong University, Xi'an 710049, China, [3]Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China, [4]School of Materials Science and Engineering, Tongji University, Shanghai, 201804, China
  • 相关基金:This work was supported by the National Natural Science Foundation of China (No. 51222104) and the Fundamental Research Funds for the Central Universities.
  • 相关项目:磁学与磁性材料
中文摘要:

一条帮助锂的途径为太古的石墨的脱落被开发了,它允许很少层 graphene nanosheets 的大规模准备。这个过程包含意外物理插入和脱落,和这个方法准备的 graphene nanosheets 揭示没受到干扰的 sp < 啜 class= “ a-plus-plus ” > 2 -hybridized 结构。可能的二拍子的圆舞机制,包含在石墨层和一个随后的 lithiation 过程的边附近被套住的否定费用,被建议在石墨夹层内解释锂的插入。如果必要,现在的脱落能被重复并且更薄(单身者或 23 层) graphene 能在大规模上被完成。这个简单过程为太古的石墨的脱落提供一个有效过程,它可能支持 graphene 的未来应用程序。

英文摘要:

A lithium-assisted approach has been developed for the exfoliation of pristine graphite, which allows the large-scale preparation of few-layer graphene nanosheets. The process involves an unexpected physical insertion and exfoliafion, and the graphene nanosheets prepared by this method reveal undisturbed sp2-hybridized structures. A possible two-step mechanism, which involves the negative charge being trapped around the edges of the graphite layers and a subsequent lithiation process, is proposed to explain the insertion of lithium inside the graphite interlayers. If necessary, the present exfoliation can be repeated and thinner (single or 2-3 layer) graphene can be achieved on a large scale. This simple process provides an efficient process for the exfoliation of pristine graphite, which might promote the future applications of graphene.

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期刊信息
  • 《纳米研究:英文版》
  • 主管单位:中华人民共和国教育部
  • 主办单位:清华大学 中国化学会
  • 主编:戴宏杰 李亚栋
  • 地址:北京市海淀区清华大学学研大厦A座5-7层
  • 邮编:100084
  • 邮箱:zhangjin@mail.tup.tsinghua.edu.cn
  • 电话:010-62783933
  • 国际标准刊号:ISSN:1998-0124
  • 国内统一刊号:ISSN:11-5974/O4
  • 邮发代号:
  • 获奖情况:
  • 第三届中国出版政府奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),英国科学文摘数据库
  • 被引量:60