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纳米微晶纤维素替代炭黑补强天然橡胶
  • ISSN号：1000-565X
  • 期刊名称：华南理工大学学报(自然科学版)
  • 时间：2012.4.15
  • 页码：101-106
  • 分类：TQ351.47[化学工程]
  • 作者机构：[1]华南理工大学材料科学与工程学院,广州510640
  • 相关基金：国家自然科学基金（项目号51173046）、国家自然科学基金-广东省联合基金（项目号U1134005）资助项目;
  • 相关项目：高性能轮胎用橡胶基纳米复合材料的制备、结构与性能
作者： 林路|罗远芳|贾德民|Gu Ju Lin Lu Luo Yuan-fang Jia De-min (School of M|
关键词： 纳米微晶纤维素, 天然橡胶, 硫化特性, 老化性能, 热性能
中文摘要：

本文研究了纳米微晶纤维素（NCC）对炭黑（cB）补强天然橡胶（NR）硫化特性、老化性能和热稳定性能的影响。制备出了填料总份数为45phr，NCC／CB填充比例为o／45，5／40，10／35，15／30，20／25phr的NR／NCC／CB复合材料。测试结果表明随NCC替代cB的份数增加扭矩降低、焦烧时间变长、正硫化时间变短、硫化速率常数变大，说明NCC具有一定程度的促硫化作用；当NCC替代10phrCB时，体系的活化能低于未替代的复合材料；粘合剂RH的加入使焦烧时间缩短、扭矩提高。热空气老化实验表明：适量NCc@cB的取代、RH的加入均有利于提高复合材料的耐老化性能；高温热老化实验显示，NCC和RH的加入提高了高温下的储能模量，含10phrNCC的复合材料表现出最好的耐高温性能；老化前后的应变扫描实验也表明了同样的趋势。热失重分析说明，NCC部分替代炭黑使复合材料的5%失重温度略微下降。NCC对CB的取代使表观交联密度降低，RH的加入则使表观交联密度整体提高。

同期刊论文项目
纳米微晶纤维素及其橡胶复合材料的制备、结构与性能
期刊论文 26 会议论文 4 专利 2 著作 1
高性能轮胎用橡胶基纳米复合材料的制备、结构与性能
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期刊信息
  • 《华南理工大学学报：自然科学版》
  • 北大核心期刊（2011版）
  • 主管单位:国家教育部科技司
  • 主办单位:华南理工大学
  • 主编：李元元
  • 地址：广州市天河区五山路华南理工大学17号楼
  • 邮编：510640
  • 邮箱：journal@scut.edu.cn
  • 电话：
  • 国际标准刊号：ISSN：1000-565X
  • 国内统一刊号：ISSN：44-1251/T
  • 邮发代号:46-174
  • 获奖情况:
  • 本学报荣获1996年国家教委系统优秀科技期刊二等奖...,1999年荣获全国优秀高校自然科学学报及教育部优秀...,2001年荣获广东省优秀期刊奖和广东省优秀科技期刊...,2004年获全国高校优秀科技期刊二等奖,2006年获首届教育部优秀科技期刊奖,2008年荣获第二届教育部优秀科技期刊奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国科学文摘数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:22954